Using nanoporous ceramic composite membranes to remove sulphur dioxide and to recover water vapor in flue gas is a new method, and this paper studied the effects of sulphur dioxide on the water recovery process. In this study, the outer-side coating of hollow nanoporous ceramic composite membrane is selected as the study object. In the membrane module for desulphurization, one end of membrane is closed to create the high-pressure environment inside membrane to ensure that the cooling water in the membrane penetrates the outer surface of the membrane to form a stable water film which can absorb sulphur dioxide from flue gas. In the membrane module for recovering water, using a vacuum pump to create micro-negative pressure environment inside membrane, and then water vapor and condensate can penetrate through the membrane under pressure difference. Based on the ceramic composite membrane module, an integrated experimental platform for desulphurization and water recovery is constructed, and the mathematical model for predicting water recovery performance is established. According to the experimental and theoretical results, the mathematical model can predict the water recovery performance of the ceramic composite membrane.