The electrocoalescence of droplets plays a crucial role in various fields. However, studies on the effects of droplet radius on the electrocoalescence behaviors of droplets have not been conducted until now. In this work, the electrocoalescence behaviors of two unequally sized conducting droplets are investigated via molecular dynamics (MD) simulations. The influences of electric field strength and droplet radius on the electrocoalescence behaviors of two unequally sized droplets are investigated. When the electric field strength increases, the contact cone angle between the droplets increases, and the two droplets are more likely to partially coalesce and bounce. When the radius of the smaller droplet between the two droplets increases at the same electric field strength, the contact cone angle, daughter droplet size, and ions in the daughter droplet increase, whereas the critical electric field strength (E-d) for generating the daughter droplet decreases. Furthermore, the daughter droplet is ejected from the smaller droplet when the two droplets have different radii.