Przemysl Chemiczny, Vol.97, No.10, 1693-1697, 2018
Fick diffusion coefficients in concentrated ethanol-water solutions. Evaluation of thermodynamic models of activity coefficients
Fick diffusion coeffs. were detd. at 298-346 K by using 4 models of fractional activity coeffs. to compare them with literature data. Relative differences between calcd. and exptl. values were small for all models used at <= 313 K but they increased with increasing temp. to 346 K reaching 22-24% for the best model.