The S(N)2 Reaction in the Solid-State - An Unusual, B(Al)2 Aminolysis of an Ester Group in Crystalline (+/-)-2-Amino-2’-Hydroxy-3’-(Methoxycarbonyl)-1,1’-Binaphthyl Elucidated by X-Ray-Diffraction and Isotopic Labeling - New Experimental-Evidence for Linearity in S(N)2 Substitution

Smrcina M; Vyskocil S; Hanus V; Polasek M; Langer V; Chew BG; Zax DB; Verrier H; Harper K; Claxton TA; Kocovsky P

Journal of the American Chemical Society, Vol.118, No.2, 487-488, 1996

DOI10.1021/ja951920y Export Citation

The S(N)2 Reaction in the Solid-State - An Unusual, B(Al)2 Aminolysis of an Ester Group in Crystalline (+/-)-2-Amino-2’-Hydroxy-3’-(Methoxycarbonyl)-1,1’-Binaphthyl Elucidated by X-Ray-Diffraction and Isotopic Labeling - New Experimental-Evidence for Linearity in S(N)2 Substitution

Smrcina M, Vyskocil S, Hanus V, Polasek M, Langer V, Chew BG, Zax DB, Verrier H, Harper K, Claxton TA, Kocovsky P

Keywords:METHYL PARA-DIMETHYLAMINOBENZENESULFONATE;ORGANIC-REACTIONS;MECHANISM;REARRANGEMENT;DERIVATIVES