화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.75, 100-107, July, 2019
DOI10.1016/j.jiec.2019.03.007  Export Citation
Multi-channel-contained few-layered MoSe2 nanosheet/N-doped carbon hybrid nanofibers prepared using diethylenetriamine as anodes for high-performance sodium-ion batteries
Sun Young Jeong, Subrata Ghosh1, Jae-Kwang Kim2, Dong-Won Kang3, Sang Mun Jeong1, †, Yun Chan Kang4, †, and Jung Sang Cho†
  • Department of Engineering Chemistry, Chungbuk National University, Chungbuk 361-763, Republic of Korea
  • 1Department of Chemical Engineering, Chungbuk National University, Chungbuk 361-763, Republic of Korea
  • 2Department of Solar & Energy Engineering, Cheongju University, Cheongju, Chungbuk, 28503, Republic of Korea
  • 3School of Energy Systems Engineering, Chung-Ang University, Seoul 06974, Republic of Korea
  • 4Department of Materials Science and Engineering, Korea University, Anam-Dong, Seongbuk-Gu, Seoul 136-713, Republic of Korea
E-mail:, ,
A facile new strategy for the synthesis of multi-channel-contained N-doped carbon nanofibers composed of few-layered MoSe2 nanosheets (denoted as MC-NCNF/MoSe2) was introduced and the composite was demonstrated as an anode material for sodium-ion batteries. This was the first time that diethylenetri- amine was introduced as a pore generator in the electrospinning process and played a key role in generating multi-channels in the structure by phase-separation from the molybdenum salt and subsequent volatilization without any additional process. Polyvinylpyrrolidone was used as a carbon precursor and played the role of a N-doping source for the carbon matrix. MC-NCNF/MoSe2 achieved a high reversible discharge capacity of 386 mA h g-1 at a current density of 0.5 A g-1 after the 300th cycle and superior rate capability of 285 mA h g-1 at 10.0 A g-1. The multi-channeled structure of MC-NCNF/ MoSe2 facilitated effective Na+ and electron diffusion during repeated discharge/charge processes and accommodated the huge volume expansion of the MoSe2 nanosheets induced by electrochemical reaction of the Na+ ion.
Keywords:Molybdenum diselenide;Sodium ion batteries;Anodes;Multi-channel;Nanofibers;Electrospinning
  1. Sun B, Li P, Zhang J, Wang D, Munroe P, Wang C, Notten PH, Wang G, Adv. Mater., 30, 180133 (2018)
  2. Kim SW, Seo DH, Ma X, Ceder G, Kang K, Adv. Eng. Mater., 2, 710 (2012)
  3. Sun J, Lee HW, Pasta M, Yuan HT, Zheng GY, Sun YM, Li YZ, Cui Y, Nat. Nanotechnol., 10(11), 980 (2015)
  4. Slater MD, Kim D, Lee E, Johnson CS, Adv. Funct. Mater., 23(8), 947 (2013)
  5. Li Z, Ding J, Mitlin D, Accounts Chem. Res., 48, 1657 (2015)
  6. Zhao L, Zhao J, Hu YS, Li H, Zhou Z, Armand M, Chen L, Adv. Eng. Mater., 2, 962 (2012)
  7. Zhu Y, Han X, Xu Y, Liu Y, Zheng S, Xu K, Hu L, Wang C, ACS Nano, 7, 6378 (2013)
  8. Yuan S, Huang XL, Ma DL, Wang HG, Meng FZ, Zhang XB, Adv. Mater., 26(14), 2273 (2014)
  9. Cho JS, Lee SY, Lee JK, Kang YC, ACS Appl. Mater. Interfaces, 8, 21343 (2016)
  10. Wu Y, Jiang Y, Shi J, Gu L, Yu Y, Small, 13, 170012 (2017)
  11. Liu YC, Zhang N, Jiao LF, Chen J, Adv. Mater., 27(42), 6702 (2015)
  12. Li W, Zeng L, Yang Z, Gu L, Wang J, Liu X, Cheng J, Yu Y, Nanoscale, 6, 693 (2014)
  13. Cho JS, Park JS, Kang YC, Nano Res., 10, 897 (2017)
  14. Cho JS, Ju HS, Lee JK, Kang YC, Nanoscale, 9, 1942 (2017)
  15. Qu BH, Ma CZ, Ji G, Xu CH, Xu J, Meng YS, Wang TH, Lee JY, Adv. Mater., 26(23), 3854 (2014)
  16. David L, Bhandavat R, Singh G, ACS Nano, 8, 1759 (2014)
  17. Chao D, Liang P, Chen Z, Bai L, Shen H, Liu X, Xia X, Zhao Y, Savilov SV, Lin J, ACS Nano, 10, 10211 (2016)
  18. Park GD, Kim JH, Park SK, Kang YC, ACS Appl. Mater. Interfaces, 9, 10673 (2017)
  19. Tang Y, Zhao Z, Wang Y, Dong Y, Liu Y, Wang X, Qiu J, ACS Appl. Mater. Interfaces, 8, 32324 (2016)
  20. Xie D, Xia X, Zhong Y, Wang Y, Wang D, Wang X, Adv. Eng. Mater., 7, 160180 (2017)
  21. Niu F, Yang J, Wang N, Zhang D, Fan W, Yang J, Qian Y, Adv. Funct. Mater., 27, 170052 (2017)
  22. Jeong SY, Park SK, Kang YC, Cho JS, Chem. Eng. J., 351, 559 (2018)
  23. Zhu C, Mu X, van Aken PA, Yu Y, Maier J, Angew. Chem.-Int. Edit., 126, 2184 (2014)
  24. Lu YY, Zhao Q, Zhang N, Lei KX, Li FJ, Chen J, Adv. Funct. Mater., 26(6), 911 (2016)
  25. Xia Y, Wang BB, Zhao XJ, Wang G, Wang H, Electrochim. Acta, 187, 55 (2016)
  26. Liu Q, Li XL, Xiao ZR, Zhou Y, Chen HP, Khalil A, Xiang T, Xu JQ, Chu WS, Wu XJ, Yang JL, Wang CM, Xiong YJ, Jin CH, Ajayan PM, Song L, Adv. Mater., 27(33), 4837 (2015)
  27. Park SK, Kang YC, ACS Appl. Mater. Interfaces, 10, 17203 (2018)
  28. Cao Y, Xiao L, Sushko ML, Wang W, Schwenzer B, Xiao J, Nie Z, Saraf LV, Yang Z, Liu J, Nano Lett., 12, 3783 (2012)
  29. Vishwanath S, Liu X, Rouvimov S, Mende PC, Azcatl A, McDonnell S, Wallace RM, Feenstra RM, Furdyna JK, Jena D, 2D Mater, 2, 024007 (2015)
  30. Sun Y, Hu X, Jimmy CY, Li Q, Luo W, Yuan L, Zhang W, Huang Y, Energy Environ. Sci., 4, 2870 (2011)
  31. Zhou J, Yang J, Xu Z, Zhang T, Chen Z, Wang J, J. Mater. Chem. A, 5, 9350 (2017)
  32. Park SK, Kim JK, Kang YC, J. Mater. Chem. A, 5, 18823 (2017)
  33. Yu JC, Hu X, Li Q, Zheng Z, Xu Y, Chem.-Eur. J., 12, 548 (2006)
  34. Kim JH, Kang YC, Small, 13, 170158 (2017)
  35. Li R, Wang S, Wang W, Cao M, Phys. Chem. Chem. Phys, 17, 24803 (2015)
  36. Li H, Su Y, Sun WW, Wang Y, Adv. Funct. Mater., 26(45), 8345 (2016)
  37. Shen G, Sun X, Zhang H, Liu Y, Zhang J, Meka A, Zhou L, Yu C, J. Mater. Chem. A, 3, 24041 (2015)
  38. Zhuang M, Ding Y, Ou X, Luo Z, Nanoscale, 9, 4652 (2017)
  39. Chen YY, Zhang Y, Jiang WJ, Zhang X, Dai Z, Wan LJ, Hu JS, ACS Nano, 10, 8851 (2016)
  40. Shui J, Du F, Xue C, Li Q, Dai L, ACS Nano, 8, 3015 (2014)
  41. Li Q, Cao R, Cho J, Wu G, Adv. Eng. Mater., 4, 130141 (2014)
  42. Cho JS, Hong YJ, Kang YC, ACS Nano, 9, 4026 (2015)
  43. Chen SQ, Wang Y, J. Mater. Chem., 20, 9735 (2010)
  44. Groen JC, Peffer LA, Perez-Ramı’rez J, Microporous Mesoporous Mater., 60, 1 (2003)
  45. Du HM, Jiao LF, Wang QH, Huan QN, Peng WX, Song DW, Wang YJ, Yuan HT, J. Power Sources, 196(24), 10748 (2011)
  46. Choi SH, Kang YC, Nanoscale, 7, 3965 (2015)
  47. Ding J, Wang H, Li Z, Kohandehghan A, Cui K, Xu Z, Zahiri B, Tan X, Lotfabad EM, Olsen BC, ACS Nano, 7, 11004 (2013)
  48. Wang S, Xia L, Yu L, Zhang L, Wang H, Lou XW, Adv. Eng. Mater., 6, 150221 (2016)
  49. Park JS, Jeong SY, Jeon KM, Kang YC, Cho JS, Chem. Eng. J., 339, 97 (2018)
  50. Li B, Li X, Li W, Wang Y, Uchaker E, Pei Y, Cao X, Li S, Huang B, Cao G, ChemNanoMat, 2, 281 (2016)
  51. Lei J, Li W, Li X, Cairns EJ, J. Mater. Chem., 22, 22022 (2012)
  52. Zhang H, Huang X, Noonan O, Zhou L, Yu C, Adv. Funct. Mater., 27, 160602 (2017)
  53. Cho JS, Park JS, Jeon KM, Kang YC, J. Mater. Chem. A, 5, 10632 (2017)
  54. Kong S, Dai R, Li H, Sun W, Wang Y, ACS Sustainable Chem. Eng., 3, 1830 (2015)
  55. Ren H, Yu R, Wang J, Jin Q, Yang M, Mao D, Kisailus D, Zhao H, Wang D, Nano Lett., 14, 6679 (2014)
  56. Sun X, Zhang H, Zhou L, Huang X, Yu C, Small, 12, 3732 (2016)