화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.75, 202-210, July, 2019
DOI10.1016/j.jiec.2019.03.025  Export Citation
Metal- and halide-free catalysts supported on silica and their applications to CO2 cycloaddition reactions
Hyeon-Gook Kim†, Bongkuk Seo, and Choong-Sun Lim
  • Advanced Industrial Chemistry Research Center, Advanced Convergent Chemistry Division, Korea Research Institute of Chemical Technology, 45 Jongga-ro, Jung-gu, Ulsan 44412, Republic of Korea
E-mail:
The production of cyclic carbonates from CO2 and epoxides has been extensively studied. We investigated the formation of a cyclic carbonate promoted by metal- and halide-free silica-supported alkanolamines. Moreover, we compared the obtained turnover numbers with those of the corresponding homogeneous catalysts and confirmed that the reusability of the proposed heterogeneous catalysts was enhanced by the utilization of polymer-type structures with amine/epoxy reaction around the silica. A cyclic carbonate yield of 70% and selectivity of 97% were achieved at 120 °C and 10 bar after five-fold reuse of the catalyst.
Keywords:Alkanolamine;Carbon dioxide fixation;Intramolecular effect;Organocatalysis;Propylene carbonate;Metal- and halide-free
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