Synthesis of novel and room temperature-operable palladium complexes on graphene oxide: An efficient recyclable catalyst for Suzuki-Miyaura coupling reactions

Yingjie Qian; Jaeil So; Myeong Yeon Lee; Sosan Hwang; Myung-Jong Jin; Sang Eun Shim

Journal of Industrial and Engineering Chemistry, Vol.75, 253-261, July, 2019

DOI10.1016/j.jiec.2019.03.033 Export Citation

Synthesis of novel and room temperature-operable palladium complexes on graphene oxide: An efficient recyclable catalyst for Suzuki-Miyaura coupling reactions

Yingjie Qian, Jaeil So, Myeong Yeon Lee, Sosan Hwang, Myung-Jong Jin, and Sang Eun Shim^†

Department of Chemistry & Chemical Engineering, Inha University, 100 Inha-ro, Nam-gu, Incheon 22212, South Korea

E-mail:

Novel palladium complexes composed of palladium and a conjugated ligand (imine-aldehyde) were immobilized on graphene oxide. The developed catalyst was characterized by XPS, and TEM. The novel catalyst was proven to be highly efficient for the Suzuki-Miyaura coupling reaction of aryl halides (Br, Cl) with arylboronic acids under mild conditions with a low amount of catalyst (0.1 mol%). In particular, excellent yields could be also obtained at room temperature within 1 h for monosubstituted aryl bromide coupling. Furthermore, the novel catalyst could be reused at least ten times without significant loss of its catalytic activities.

Keywords:Graphene oxide;Conjugated ligand;Palladium;Heterogeneous catalyst;Suzuki-Miyaura coupling

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