New Hexagonally Ordered Monolayer Electrode with Monodisperse Carbon/Fe3O4 Microspheres for High Performance Lithium Ion Battery Anodes

Jun-Ki Hwang; Kyung-Do Suh

Macromolecular Research, Vol.27, No.6, 572-578, June, 2019

DOI10.1007/s13233-019-7078-4 Export Citation

New Hexagonally Ordered Monolayer Electrode with Monodisperse Carbon/Fe3O4 Microspheres for High Performance Lithium Ion Battery Anodes

Jun-Ki Hwang^†, and Kyung-Do Suh

Department of Chemical Engineering, College of Engineering, Hanyang University, Seoul 04763, Korea

E-mail:

This work details the facile preparation of a hexagonally ordered monolayer electrode with monodispersed hollow C/Fe3O4 microspheres as a novel anode candidate for lithium-ion batteries. The monolayer electrode was produced by the heat treatment of a polyvinyl alcohol film comprising a monolayer of microspheres. The electrode was prepared by stamping with microspheres assembled into the monolayer, using an ordered patterning micro-framework polydimethylsiloxane on a polyvinyl alcohol spin-coated cupper foil. The morphological and structural characterizations of the monolayer electrode were conducted by optical microscopy, scanning electron microscopy, focused-ion beam scanning electron microscopy, transmission electron microscopy, and X-ray diffractometery. Although the monolayer electrode was composed of the active materials only without the use of any polymeric binder or carbon additives such as acetylene black and Super-P, the electrode exhibited a superior long-term cycling stability and rate capability with the coulombic efficiency of 99% at a high current rate due to the good structural stability and low electrical resistance as a result of the ordered monolayer structure.

Keywords:monolayer;thin film;hexagonally ordered;carbon/magnetite composite;anode materials;Li-ion battery

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[Related Articles]

[1] Muraliganth T, Murugan AV, Manthiram A, Chem. Commun., 7360 (2009).

[2] Liu H, Wang G, Wang J, Wexler D, Electrochem. Commun., 10, 1879 (2008)

[3] Xiong QQ, Lu Y, Wang XL, Gu CD, Qiao YQ, Tu JP, J. Alloy. Compd., 536, 219 (2012)

[4] Jin SL, Deng HG, Long DH, Liu XJ, Zhan LA, Liang XY, Qiao WM, Ling LC, J. Power Sources, 196(8), 3887 (2011)

[5] Zhang H, Braun PV, Nano Lett., 12, 2778 (2012)

[6] Fan X, Dou P, Jiang A, Ma D, Xu X, ACS Appl. Mater. Interfaces, 6, 22282 (2014)

[7] Yiping T, Xiaoxu T, Guangya H, Guoqu Z, Electrochim Acta, 117, 172 (2014)

[8] Liu JY, Zhang HG, Wang JJ, Cho J, Pikul JH, Epstein ES, Huang XJ, Liu JH, King WP, Braun PV, Adv. Mater., 26(41), 7096 (2014)

[9] Poizot P, Laruelle S, Grugeon S, Dupont L, Tarascon JM, J. Power Sources, 97-98, 235 (2001)

[10] Laruelle S, Grugeon S, Poizot P, Dolle M, Dupont L, Tarascon JM, J. Electrochem. Soc., 149(5), A627 (2002)

[11] He Y, Huang L, Cai JS, Zheng XM, Sun SG, Electrochim. Acta, 55(3), 1140 (2010)

[12] Lee GH, Park JG, Sung YM, Chung KY, Cho WI, Kim DW, Nanotechnology, 20, 295205 (2009)

[13] Yoon T, Chae C, Sun YK, Zhao X, Kung HH, Lee JK, J. Mater. Chem., 21, 17325 (2011)

[14] Hao Q, Lei D, Yin X, Zhang M, Liu S, Li Q, Chen L, Wang T, J. Solid State Electrochem., 15, 2563 (2011)

[15] Baksh MM, Jaros M, Groves JT, Nature, 427, 139 (2004)

[16] Zhang JH, Li YF, Zhang XM, Yang B, Adv. Mater., 22(38), 4249 (2010)

[17] Marlow F, Muldarisnur, Sharifi P, Brinkmann R, Mendive C, Angew. Chem.-Int. Edit., 48, 6212 (2009)

[18] Li X, Wang TQ, Zhang JH, Yan X, Zhang XM, Zhu DF, Li W, Zhang X, Yang B, Langmuir, 26(4), 2930 (2010)

[19] Park C, Lee T, Xia YN, Shin TJ, Myoung J, Jeong U, Adv. Mater., 26(27), 4633 (2014)

[20] Hwang JK, Lim HS, Sun YK, Suh KD, J. Power Sources, 244, 538 (2013)

[21] Chou SL, Wang JZ, Wexler D, Konstantinov K, Zhong C, Liu HK, Dou SX, J. Mater. Chem., 20, 2092 (2010)

[22] Hang BT, Doi T, Okada S, Yamaki JI, J. Power Sources, 174(2), 493 (2007)

[23] Balaya P, Li H, Kienle L, Maier J, Adv. Funct. Mater., 13(8), 621 (2003)