Journal of Industrial and Engineering Chemistry, Vol.76, 39-74, August, 2019
Review on Cu2SnS3, Cu3SnS4, and Cu4SnS4 thin films and their photovoltaic performance
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The rapid progress on the Cu-Sn-S (Cu2SnS3, Cu3SnS4, and Cu4SnS4) solar cells has opened a new avenue to generate the electrical energy at ultra-low-cost. Therefore, the progress in the deposition of Cu2SnS3, Cu3SnS4, and Cu4SnS4 thin films by various chemical and physical methods is reviewed comprehensively. This article briefly describes (i) the phase diagrams of Cu-Sn-S, (ii) the bulk properties of Cu2SnS3, Cu3SnS4, and Cu4SnS4, (iii) the effect of deposition conditions on the phase formation, (iv) the physical properties of Cu2SnS3, Cu3SnS4, and Cu4SnS4 thin films, and (v) the photovoltaic performance of Cu2SnS3, Cu3SnS4, and Cu4SnS4 solar cells.
Keywords:Cu2SnS3;Cu3SnS4;Cu4SnS4;Earth-abundant absorber material;Physical properties;Photovoltaic performance
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