화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.76, 122-132, August, 2019
Application of FSM-16 impregnated by TiO2 as an efficient photocatalyst for elimination of benzothiophene and dibenzothiophene, adsorptive removal of degradation products by MCM-41
E-mail:
A novel photocatalyst was prepared by immobilization of TiO2 on the surface of FSM-16 catalyst support, and was characterized by different techniques. Optical properties of synthesized sample studied by diffuse reflectance spectroscopy, and photoluminescence analysis indicated that after immobilization the bang gap energy of TiO2 was shifted to visible region, and electron-hole recombination was reduced. The degradation tests performed at various conditions under UV and visible lights showed that at optimized conditions 91% of benzothiophene and 77% of dibenzothiophene were eliminated. Degradation products were identified by GC?MS, and were removed by MCM-41 adsorbent. The used photocatalyst was highly regenerable.
  1. Jing JY, Liu MH, Colvin VL, Li WY, Yu WW, J. Mol. Catal. A-Chem., 351, 17 (2011)
  2. Li Y, Zhao D, Lin J, Yuan Q, Energy Sources, Part A, 31, 191 (2009)
  3. Takbiri M, Mohammadi T, Pak A, NSMSI, 31, 1 (2012)
  4. Babich IV, Moulijn JA, Fuel, 82(6), 607 (2003)
  5. Nagamatsu S, Yoshida J, Petrotech, 23, 110 (2000)
  6. Faghihian H, Sadeghinia R, Adv. Chem. Eng. Res., 3, 211 (2014)
  7. Joo SH, Zhao DY, J. Hazard. Mater., 322, 29 (2017)
  8. Kim KH, Ihm SK, J. Hazard. Mater., 186(1), 16 (2011)
  9. Huang H, He Y, Li X, Li M, Zeng C, Dong F, Du X, Zhang T, Zhang Y, J. Mater. Chem. A, 3, 24547 (2015)
  10. Huang H, Li X, Wang J, Dong F, Chu PK, Zhang T, Zhang Y, ACS Catal, 5, 4094 (2015)
  11. Huang HW, Xiao K, He Y, Zhang TR, Dong F, Du X, Zhang YH, Appl. Catal. B: Environ., 199, 75 (2016)
  12. Huang H, Tu S, Zeng C, Zhang T, Reshak AH, Zhang Y, Angew. Chem.-Int. Edit., 56, 11860 (2017)
  13. Kuo CY, Wu CH, Chen ST, Desalin. Water Treat., 52, 834 (2014)
  14. Samarghandi MR, Yang JK, Lee SM, Giahi O, Shirzad-Siboni M, Desalin. Water Treat., 52, 1531 (2014)
  15. Sunada F, Heller A, Environ. Sci. Technol., 32, 282 (1998)
  16. Chen Y, Wang K, Lou L, J. Photochem. Photobiol. A-Chem., 163, 281 (2004)
  17. Xu Y, Zheng W, Liu W, J. Photochem. Photobiol. A-Chem., 122, 57 (1999)
  18. Herrmann JM, Matos J, Disdier J, Guillard C, Laine J, Malato S, Blanco J, Catal. Today, 54(2-3), 255 (1999)
  19. Yoneyama H, Torimoto T, Catal. Today, 58(2-3), 133 (2000)
  20. Ooka C, Yoshida H, Suzuki K, Hattori T, Microporous Mesoporous Mater., 67, 143 (2004)
  21. Sun Z, Chen Y, Ke Q, Yang Y, Yuan J, J. Photochem. Photobiol. A-Chem., 149, 169 (2002)
  22. Kang MG, Park HS, Kim KJ, J. Photochem. Photobiol. A-Chem., 149, 175 (2002)
  23. Bhattacharyya A, Kawi S, Ray MB, Catal. Today, 98(3), 431 (2004)
  24. Matsumoto A, Sasaki T, Nishimiya N, Tsutsumi K, Colloids Surf. A: Physicochem. Eng. Asp., 203, 185 (2002)
  25. Zabihi-Mobarakeh H, Nezamzadeh-Ejhieh A, J. Ind. Eng. Chem., 26, 315 (2015)
  26. Li X, Pi Y, Xia Q, Li Z, Xiao J, Appl. Catal. B: Environ., 41, 5077 (2016)
  27. Torki F, Faghihian H, J. Photochem. Photobiol. A-Chem., 338, 49 (2017)
  28. Garg S, Soni K, Kumar M, Bhaskar T, Gupta JK, Rao KSR, Dhar GM, Catal. Today, 198(1), 263 (2012)
  29. Yang GJ, Li CJ, Han F, Huang XC, J. Vac. Sci. Technol. B, 22(5), 2364 (2004)
  30. Kitayama Y, Asano H, Kodama T, Abe J, J. Porous Mater., 5, 139 (1998)
  31. Borrego T, Andrade M, Pinto ML, Silva AR, Carvalho AP, Rocha J, Freire C, Pires J, J. Colloid Interface Sci., 344(2), 603 (2010)
  32. Nezamzadeh-Ejhieh A, Zabihi-Mobarakeh H, J. Ind. Eng. Chem., 20(4), 1421 (2014)
  33. Hazrati N, Abdouss M, Vahid A, MiranBeigi AA, Mohammadalizadeh A, Int. J. Environ. Sci. Technol., 11, 997 (2014)
  34. Fatimah I, Sopia L, AIP Conf. Proc., 1823, 020124 (2017)
  35. Sugiyama S, Kato Y, Wada T, Ogawa S, Nakagawa K, Sotowa KI, Top. Catal., 53, 550 (2010)
  36. Esmaili-Hafshejani J, Nezamzadeh-Ejhieh A, J. Hazard. Mater., 316, 194 (2016)
  37. Dzimbeg-Malcic V, Barbaric-Mikocevic Z, Itric K, Tech. Gaz., 18, 117 (2011)
  38. Mehrabadi Z, Faghihian H, J. Photochem. Photobiol. A-Chem., 356, 102 (2018)
  39. Tauc J, Grigorovici R, Vancu A, Phys. Status Solidi B, 15, 627 (1996)
  40. Nezamzadeh-Ejhieh A, Moazzeni N, J. Ind. Eng. Chem., 19(5), 1433 (2013)
  41. Choina J, Kosslick H, Fischer C, Flechsig GU, Frunza L, Schulz A, Appl. Catal. B: Environ., 129, 589 (2013)
  42. Matsuzawa S, Tanaka J, Sato S, Ibusuki T, J. Photochem. Photobiol. A-Chem., 149, 183 (2002)
  43. Mijin D, Radivojevic J, Jovancic P, Chem. Ind. Chem. Eng. Q., 13, 33 (2007)
  44. Zhao N, Li S, Wang J, Zhang R, Gao R, Zhao J, Wang J, J. Solid State Chem., 225, 347 (2015)
  45. Long ZY, Yang CP, Zeng GM, Peng LY, Dai CH, He HJ, Fuel, 130, 19 (2014)
  46. Ji Y, Zhou L, Ferronato C, Yang X, Salvador A, Zeng C, Chovelon JM, J. Photochem. Photobiol. A-Chem., 254, 35 (2013)
  47. Nezamzadeh-Ejhieh A, Karimi-Shamsabadi M, Chem. Eng. J., 228, 631 (2013)
  48. Huang D, Wang YJ, Cui YC, Luo GS, Microporous Mesoporous Mater., 116, 378 (2008)
  49. Moradi S, Vossoughi M, Feilizadeh M, EsmaeilZakeri SM, Mohammadi MM, Rashtchian D, YoosefiBooshehri A, Res. Chem. Intermed., 41, 4151 (2015)
  50. San N, Hatipoglu A, Kocturk G, Cinar Z, J. Photochem. Photobiol. A-Chem., 146, 189 (2002)
  51. Xu JC, Shi YL, Huang JE, Wang B, Li HL, J. Mol. Catal. A-Chem., 219, 315 (2004)
  52. Luo GQ, Kang LH, Zhu MY, Dai B, Fuel Process. Technol., 118, 20 (2014)
  53. Reddy EP, Sun B, Smirniotis PG, J. Phys. Chem. B, 108(44), 17198 (2004)
  54. Tseng DH, Juang LC, Huang HH, Int. J. Photoenergy, 2012, 1 (2012)
  55. Qiu JH, Wang GH, Zhang YQ, Zeng DL, Chen Y, Fuel, 147, 195 (2015)
  56. Torki F, Faghihian H, RSC Adv., 86, 54651 (2017)
  57. Pelaez M, Falaras P, Likodimos V, O'Shea K, de la Cruz AA, Dunlop PSM, Byrne JA, Dionysiou DD, J. Mol. Catal. A-Chem., 425, 183 (2016)
  58. Yan XM, Lei JH, Liu D, Wu YC, Guo LP, J. Chin. Chem. Soc., 54, 911 (2007)