Fabrication of spherical CNT skeins formed by self-entangled fibers from hollow type mesoporous silica microcapsules

Geun Woo Park; Jae Bin Yoo; Geon-Joong Kim

Journal of Industrial and Engineering Chemistry, Vol.76, 457-466, August, 2019

DOI10.1016/j.jiec.2019.04.013 Export Citation

Fabrication of spherical CNT skeins formed by self-entangled fibers from hollow type mesoporous silica microcapsules

Geun Woo Park, Jae Bin Yoo, and Geon-Joong Kim^†

Graduate School of Chemistry and Chemical Engineering, Inha University, 100 Inha-ro, Michuhol-gu, Incheon 22212, South Korea

E-mail:

Various type CNT balls were fabricated using porous hollow microcapsules, and they were characterized by XRD, TEM and N2 adsorption/desorption analysis. The CNT Balls tangled together showed extremely improved thermal and electrical properties as compared to the fibrous CNTs. Notably increased strain values, such as more than 30% strains at fixed stress, with high toughness have resulted in for those entangled CNT skeins. Even though the CNT skeins entangled together with fibrous bundles have been fabricated as a multi wall-type, they could be applied successfully as a DNA separator and highly conducting electrochemical/rheological materials.

Keywords:Hollow porous microcapsules;Reverse replication;Carbon nano-urchins;Entangled spherical CNT lumps

[References]

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Frysz CA, Shui X, Chung DDL, J. Power Sources, 58, 41 (1996)
Miranda-Hernandez M, Ayala JA, Rincon ME, J. Solid State Electrochem., 7, 264 (2003)
Gao T, Woodka MD, Brunschwig BS, Lewis NS, Chem. Mater., 18, 5193 (2006)
Zhu M, Weber CJ, Yang Y, Konuma M, Starke U, Kern K, Bittner AM, Carbon, 46, 1829 (2008)
Tamai H, Kouzu M, Morita M, Yasuda H, Electrochem. Solid-State Lett., 6, A214 (2003)
Yamada Y, Tanaike O, Liang TT, Hatori H, Shiraishi S, Oya A, Electrochem. Solid State Lett., 5(12), A283 (2002)
Yoon S, Lee JW, Hyeon T, Oh SM, J. Electrochem. Soc., 147(7), 2507 (2000)
Fuertes AB, Lota G, Centeno TA, Frackowiak E, Electrochim. Acta, 50(14), 2799 (2005)
Han S, Lee K, Oh S, Hyeon T, Carbon, 41, 1049 (2003)
Yu J, Yoon SB, Chai GS, Carbon, 39, 1442 (2001)
Ko JM, Kim KM, Mat. Chem. Phys., 114, 837 (2009)
Raymundo-Pinero E, Khomenko V, Frackowiakm E, Beguin FJ, Electrochem. Soc., 152, A229 (2005)
Wang GX, Zhang BL, Yu ZL, Qu MZ, Solid State Ion., 176, 1169 (2005)
Fan Z, Chen J, Wang M, Cui K, Zhou H, Kuang Y, Diamond Relat. Mater., 15, 1478 (2006)
Subramanian V, Zhu H, Wei B, Electrochem. Commun., 8, 827 (2006)
Barisci JN, Wallace GG, Baughman RHJ, Electrochem. Soc., 147, 4580 (2000)
An KH, Kim WS, Park YS, Choi YC, Lee SM, Chung DC, Bae DJ, Lim SC, Lee YH, Adv. Mater., 13(7), 497 (2001)
An KH, Kim WS, Park YS, Moon JM, Bae DJ, Lim SC, Lee YS, Lee YH, Adv. Funct. Mater., 11(5), 387 (2001)
Peigney A, Laurent CH, Flahaut E, Rousset A, Carbon, 39, 507 (2001)
(a)Lee J, Kim J, Hyeon T, Adv. Mater. 18, 2073 (2006); b) Kim M, Yoon SB, Sohn K, Kim JY, Shin CH, Hyeon T, Yu JS, Microporous Mesoporous Mater. 63, 1 (2003); (c) Yoon SB, Sohn K, Kim JY, Shin CH, Yu JS, Hyeon T, Adv. Mater. 14, 19(2002).
Piao Y, An K, Kim J, Yu T, Hyeon T, J. Mater. Chem., 16, 2984 (2006)
Kim SW, Kim M, Lee WY, Hyeon T, J. Am. Chem. Soc., 124(26), 7642 (2002)
Jiang P, Berton JF, Colvin VL, Science, 291, 453 (2001)
Li YS, Shi JL, Hua ZL, Chen HR, Ruan ML, Yan DS, Nano Lett., 3, 609 (2003)
Gittins D, Caruso IF, Adv. Mater., 13, 740 (2003)
Wang XD, Yang WI, Tang Y, Wang YJ, Fu SK, Gao Z, Chem. Commun., 2161 (2002).
Guo XF, Kim YS, Kim GJ, J. Phys. Chem. C, 113, 8313 (2009)
Kim YS, Guo XF, Kim GJ, J. Phys. Chem. Solids, 71, 616 (2010)
Jeon SG, Yang JY, Park KW, Kim GJ, Bull. Korean Chem. Soc., 35, 3583 (2014)
Jang DY, Jang HG, Kim GR, Kim GJ, Bull. Korean Chem. Soc., 32, 3274 (2011)
Kim GJ, Guo XF, J. Phys. Chem. Solids, 71, 612 (2010)
Guo XF, Kim GJ, Bull. Korean Chem. Soc., 32, 186 (2011)
Guo XF, Kim YS, Kim GJ, J. Nanosci. Nanotechnol., 11, 1672 (2011)
Choi SD, Yang HC, Lee YW, Kim GJ, Adv. Porous Mater., 5, 44 (2017)
Choi SD, Lee JH, Park DM, Kim GJ, Bull. Korean Chem. Soc., 34, 2155 (2013)
Guo XF, Kim YS, Kim GJ, Catal. Today, 150(1-2), 22 (2010)
Kim YS, Guo XF, Kim GJ, Catal. Today, 150(1-2), 91 (2010)

[1] Hyeon T, Han S, Sung YE, Park KW, Kim YW, Angew. Chem.-Int. Edit., 42, 4352 (2003)

[2] Frysz CA, Shui X, Chung DDL, J. Power Sources, 58, 41 (1996)

[3] Miranda-Hernandez M, Ayala JA, Rincon ME, J. Solid State Electrochem., 7, 264 (2003)

[4] Gao T, Woodka MD, Brunschwig BS, Lewis NS, Chem. Mater., 18, 5193 (2006)

[5] Zhu M, Weber CJ, Yang Y, Konuma M, Starke U, Kern K, Bittner AM, Carbon, 46, 1829 (2008)

[6] Tamai H, Kouzu M, Morita M, Yasuda H, Electrochem. Solid-State Lett., 6, A214 (2003)

[7] Yamada Y, Tanaike O, Liang TT, Hatori H, Shiraishi S, Oya A, Electrochem. Solid State Lett., 5(12), A283 (2002)

[8] Yoon S, Lee JW, Hyeon T, Oh SM, J. Electrochem. Soc., 147(7), 2507 (2000)

[9] Fuertes AB, Lota G, Centeno TA, Frackowiak E, Electrochim. Acta, 50(14), 2799 (2005)

[10] Han S, Lee K, Oh S, Hyeon T, Carbon, 41, 1049 (2003)

[11] Yu J, Yoon SB, Chai GS, Carbon, 39, 1442 (2001)

[12] Ko JM, Kim KM, Mat. Chem. Phys., 114, 837 (2009)

[13] Raymundo-Pinero E, Khomenko V, Frackowiakm E, Beguin FJ, Electrochem. Soc., 152, A229 (2005)

[14] Wang GX, Zhang BL, Yu ZL, Qu MZ, Solid State Ion., 176, 1169 (2005)

[15] Fan Z, Chen J, Wang M, Cui K, Zhou H, Kuang Y, Diamond Relat. Mater., 15, 1478 (2006)

[16] Subramanian V, Zhu H, Wei B, Electrochem. Commun., 8, 827 (2006)

[17] Barisci JN, Wallace GG, Baughman RHJ, Electrochem. Soc., 147, 4580 (2000)

[18] An KH, Kim WS, Park YS, Choi YC, Lee SM, Chung DC, Bae DJ, Lim SC, Lee YH, Adv. Mater., 13(7), 497 (2001)

[19] An KH, Kim WS, Park YS, Moon JM, Bae DJ, Lim SC, Lee YS, Lee YH, Adv. Funct. Mater., 11(5), 387 (2001)

[20] Peigney A, Laurent CH, Flahaut E, Rousset A, Carbon, 39, 507 (2001)

[21] (a)Lee J, Kim J, Hyeon T, Adv. Mater. 18, 2073 (2006); b) Kim M, Yoon SB, Sohn K, Kim JY, Shin CH, Hyeon T, Yu JS, Microporous Mesoporous Mater. 63, 1 (2003); (c) Yoon SB, Sohn K, Kim JY, Shin CH, Yu JS, Hyeon T, Adv. Mater. 14, 19(2002).

[22] Piao Y, An K, Kim J, Yu T, Hyeon T, J. Mater. Chem., 16, 2984 (2006)

[23] Kim SW, Kim M, Lee WY, Hyeon T, J. Am. Chem. Soc., 124(26), 7642 (2002)

[24] Jiang P, Berton JF, Colvin VL, Science, 291, 453 (2001)

[25] Li YS, Shi JL, Hua ZL, Chen HR, Ruan ML, Yan DS, Nano Lett., 3, 609 (2003)

[26] Gittins D, Caruso IF, Adv. Mater., 13, 740 (2003)

[27] Wang XD, Yang WI, Tang Y, Wang YJ, Fu SK, Gao Z, Chem. Commun., 2161 (2002).

[28] Guo XF, Kim YS, Kim GJ, J. Phys. Chem. C, 113, 8313 (2009)

[29] Kim YS, Guo XF, Kim GJ, J. Phys. Chem. Solids, 71, 616 (2010)

[30] Jeon SG, Yang JY, Park KW, Kim GJ, Bull. Korean Chem. Soc., 35, 3583 (2014)

[31] Jang DY, Jang HG, Kim GR, Kim GJ, Bull. Korean Chem. Soc., 32, 3274 (2011)

[32] Kim GJ, Guo XF, J. Phys. Chem. Solids, 71, 612 (2010)

[33] Guo XF, Kim GJ, Bull. Korean Chem. Soc., 32, 186 (2011)

[34] Guo XF, Kim YS, Kim GJ, J. Nanosci. Nanotechnol., 11, 1672 (2011)

[35] Choi SD, Yang HC, Lee YW, Kim GJ, Adv. Porous Mater., 5, 44 (2017)

[36] Choi SD, Lee JH, Park DM, Kim GJ, Bull. Korean Chem. Soc., 34, 2155 (2013)

[37] Guo XF, Kim YS, Kim GJ, Catal. Today, 150(1-2), 22 (2010)

[38] Kim YS, Guo XF, Kim GJ, Catal. Today, 150(1-2), 91 (2010)