Journal of Industrial and Engineering Chemistry, Vol.76, 488-499, August, 2019
Mesoporous TiO2-rutile supported MnxOy-Na2WO4: Preparation, characterization and catalytic performance in the oxidative coupling of methane
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The oxidative coupling of methane (OCM) is one of the most important direct method to convert natural gas into value added products. For the first time in literature mesoporous TiO2-rutile supported MnxOy- Na2WO4 catalyst was prepared, characterized and tested in the OCM. The activity parameters (X-CH4, SC2, Y-C2) did not change substantially during the reaction and they were mostly stable. The MnxOy- Na2WO4/mes-TiO2-rutile catalyst seems to have promising potential for the OCM. Moreover, when it is compared with commercial TiO2-rutile and TiO2-anatase supported catalysts in literature, it can be concluded that it is a candidate showing even better performance in the OCM.
Keywords:MnxOy-Na2WO4;TiO2;Rutile;Oxidative coupling of methane;OCM;Ethylene;Direct methane conversion;Mesoporous metal oxide;Support material
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