화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.77, 65-75, September, 2019
DOI10.1016/j.jiec.2019.04.001  Export Citation
Polyacrylonitrile fiber with strongly acidic electrostatic microenvironment: Highly efficient and recyclable heterogeneous catalyst for the synthesis of heterocyclic compounds
Jian Xiao1, Gang Xu1, Lu Wang1, Pengyu Li1, Wenqin Zhang1, 2, Ning Ma1, 2, †, and Minli Tao1, †
  • 1Department of Chemistry, School of Sciences, Tianjin University, Tianjin, 300072, PR China
  • 2Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin, 300072, PR China
E-mail:,
Four categories of sulfonic acid functionalized fiber catalysts with different surface microenvironments were synthesized by covalent grafting using polyacrylonitrile fiber (PANF) as the support. After the effect of acid structure on catalytic activity has been investigated by Friedlander reaction, PANEOSF was chosen for the synthesis of quinolines and coumarin derivatives with high yields and extensive substrate scope (51 examples) in ethanol or water. The effect of electrostatic microenvironment and solvent has been discussed, and a “release-catch-release-catch” catalytic pattern was proposed accordingly. PANEOSF can be easily recycled for 20 times without any decrease of catalytic activity.
Keywords:Heterogeneous catalysis;Polyacrylonitrile fibers;Recyclability;Green solvent;Heterocyclic compounds
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