화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.77, 280-290, September, 2019
DOI10.1016/j.jiec.2019.04.049  Export Citation
Degradation of diazinon pesticide using catalyzed persulfate with Fe3O4@MOF-2 nanocomposite under ultrasound irradiation
Saeed Sajjadi1, Alireza Khataee1, 2, †, Nafiseh Bagheri1, Mehmet Kobya2, Ahmet Senocak3, Erhan Demirbas3, and Aybike Gul Karaoglu2
  • 1Research Laboratory of Advanced Water and Wastewater Treatment Processes, Department of Applied Chemistry, Faculty of Chemistry, University of Tabriz, 51666-16471 Tabriz, Iran
  • 2Department of Environmental Engineering, Gebze Technical University, 41400 Gebze, Turkey
  • 3Department of Chemistry, Gebze Technical University, 41400 Gebze, Turkey
E-mail:
Herein, Fe3O4@MOF-2 (MOF: metal-organic framework) nanocomposite, as a heterogeneous nanocatalyst, was applied to activate persulfate (PS) in the attendance of ultrasonic (US) irradiation (Fe3O4@MOF-2/US/PS) for degradation of diazinon. The evaluation results showed that, in the acidic solution (pH = 3), the reaction rate constant of Fe3O4@MOF-2/US/PS system (0.0546 min-1) was more than 6-folds than that of the US/PS system (0.0079 min-1). Reducing the diazinon concentration, along with raising the Fe3O4@MOF-2 dosage and the US bath power favored the degradation of diazinon. It was found that Fe3O4@MOF-2 had fine catalytic performance and reuseibility. The diazinon decomposition pathway was proposed by GC.MS analysis.
Keywords:Advanced oxidation processes;Nanocatalyst;Ultrasonic-assisted process;Metal-organic framework
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