화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.77, 344-354, September, 2019
DOI10.1016/j.jiec.2019.04.057  Export Citation
Greener processes in the preparation of thin film nanocomposite membranes with diverse metal-organic frameworks for organic solvent nanofiltration
Lorena Paseta1, Marta Navarro1, Joaquín Coronas1, 2, and Carlos Téllez1, 2, †
  • 1Instituto de Nanociencia de Arago’n (INA) and Chemical and Environmental Engineering Department, Universidad de Zaragoza, 50018 Zaragoza, Spain
  • 2Instituto de Ciencia de Materiales de Aragón (ICMA), CSIC-Universidad de Zaragoza, 50018 Zaragoza, Spain
E-mail:
The toxic solvent dimethylformamide has been replaced by the greener dimethylsulfoxide in the casting and activation processes for the preparation of thin film composite (TFC) membranes. This methodology has been validated with the use of MOFs ZIF-8, ZIF-93 and UiO-66 as fillers for thin-film nanocomposite (TFN) membranes. These membranes were successfully applied in the organic solvent nanofiltration of sunset yellow (SY) in methanol obtaining the highest permeance when UiO-66 and ZIF-93 were used with a value of 11 L m-2 h-1 bar-1. The permeance improvements are related to the MOF porosity, polyamide-MOF layer thickness and the hydrophilic/hydrophobic character of the membrane.
Keywords:Greener preparation process;Organic solvent nanofiltration;Thin film nanocomposite;Metal-organic frameworks
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