화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.77, 432-440, September, 2019
DOI10.1016/j.jiec.2019.05.008  Export Citation
Synthesis of sulfonated catalyst from bituminous coal to catalyze esterification for biodiesel production with promoted mechanism analysis
Tang Xincheng, Niu Shengli†, Zhao Shuang, Zhang Xiangyu, Li Ximing, Yu Hewei, Lu Chunmei, and Han Kuihua
  • School of Energy and Power Engineering, Shandong University, Jinan 250061, Shandong, China
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The carbon-based heterogeneous acid catalyst is synthesized from bituminous coal through the partial carbonization and sulfonation method and applied to catalyze the esterification of oleic acid with methanol for biodiesel production. Various characterization methods are used to explain catalytic features and molecular simulation is conducted to analyze the promoted mechanism of acid catalyst in esterification. Carbon catalyst, prepared by partially carbonized at 350 °C and sulfonated at 105 °C, catalyzes esterification with biodiesel yield of 98.70%. Transition state analysis implies that acid catalyst reduces the activation energy through providing proton to promote esterification.
Keywords:Biodiesel;Esterification;Coal carbon-based heterogeneous acid;catalyst;Molecular simulation;Transition state analysis
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