Cottonseed biodiesel oxidative stability in mixture with natural antioxidants

João Paulo Almeida Freitas; Fernanda Rocha Morais França; Maria Susana Silva; Richard James Toms; Gabriel Francisco da Silva

Korean Journal of Chemical Engineering, Vol.36, No.8, 1298-1304, August, 2019

DOI10.1007/s11814-019-0287-x Export Citation

Cottonseed biodiesel oxidative stability in mixture with natural antioxidants

João Paulo Almeida Freitas^†, Fernanda Rocha Morais França¹, Maria Susana Silva², Richard James Toms³, and Gabriel Francisco da Silva⁴

Chemical Engineering Department, Federal University of Sergipe, Sergipe, Brazil
¹Chemical Engineering Department, Federal University of Alagoas, Alagoas, Brazil
²Oil and Gas Research Center, Chemical Engineering Department, Federal University of Sergipe, Sergipe, Brazil
³Centre for Environment and Sustainability, University of Surrey, Surrey, United Kingdom, UK
⁴Laboratory of Alternative Technologies, Chemical Engineering Department, Federal University of Sergipe, Sergipe, Brazil

E-mail:

We evaluated the antioxidant power of the natural extracts catechin, curcumin and quercetin on the oxidative stability of methylic cottonseed oil biodiesel by applying the simplex-centroid augmented mixture experimental design, in addition to verifying the existence and the type of synergy among the extracts. The oxidative stability was measured using Rancimat method (EN 14112) for biodiesel added with 1,000, 2,000 and 3,000 ppm of additives, and compared with the commercial synthetic antioxidant butyl hydroxyanisole at the same concentrations. All additives had a positive effect on biodiesel oxidative stability; in addition, catechin and quercetin proved to be more efficient than the synthetic antioxidant, whereas curcumin showed similar results. The results also revealed that the interactions among the extracts varied not only with the proportion in which they were added to the biodiesel, but also with the total concentration, so that the increase in concentration reduced the magnitude of the synergistic effect.

Keywords:Antioxidant;Biodiesel;Biofuel;Experimental Design;Oxidative Stability

[References]

Albuquerque MCG, Machado YL, Torres AEB, Azevedo DCS, Cavalcante CL, Firmiano LR, Parente EJS, Renew. Energy, 34(3), 857 (2009)
Knothe G, Gerpen JV, Krajl J, The biodiesel handbook, AOCS Press, Campaign (2010).
Christensen E, McCormick RL, Fuel Process. Technol., 128, 339 (2014)
Simic MG, J. Chem. Educ., 58, 125 (1981)
Frankel EN, Lipid oxidantion, Woodhead Publishing, Filadelfia (2012).
Borsato D, Galvan D, Pereira JL, Orives JR, Angilelli KG, Coppo RL, J. Braz. Chem. Soc., 25, 1984 (2014)
Maia ECR, Borsato D, Moreira I, Spacino KR, Rodrigues PRP, Gallina AL, Fuel Process. Technol., 92(9), 1750 (2011)
Rawat DS, Joshi G, Lamba BY, Tiwari AK, Kumar P, Energy, 84, 643 (2015)
de Sousa LS, de Moura CVR, de Oliveira JE, de Moura EM, Fuel, 134, 420 (2014)
Pereira DF, Silva APD, Vasconcelos VM, Aranda DAG, Silva GFD, Rev. Tecnol., 33, 156 (2012)
Huang J, Wang Y, Xie Z, Zhou Y, Zhang Y, Wan X, Eur. J. Clin. Nutr., 68, 1075 (2014)
Sueth-Santiago V, Mendes-Silva GP, Decote-Ricardo D, Lima MEF, Quim. Nova, 38, 538 (2015)
Gerin F, Sener U, Erman H, Yilmaz A, Aydin B, Armutcu F, Gurel A, Inflammation, 39, 700 (2016)
Sfgate, Foods high in catechins, http://healthyeating.sfgate.com/foods-high-catechins-4512.html (accessed 04 april 2017).
Du GJ, Zhang Z, Wen XD, Yu C, Calway T, Yuan CS, Wang CZ, Nutrients, 4 (2012)
Matsubara S, Rodriguez-Amaya DB, Food Sci. Technol., 26, 401 (2006)
Franca FRM, Menezes DS, Moreira JJS, Silva GF, Brandao ST, Congresso Brasileiro de Engenharia Quimica, Florianopolis, 1 (2014).
Borra SK, Gurumurthy P, Mahendra J, Jayamathi KM, Cherian CN, Chand R, J. Med. Plant Res., 7, 2680 (2013)
Peret-Almeida L, Naghetini CDC, Nunan EDA, Junqueira RG, Gloria MBA, Ciencia e Agrotecnologia, 32, 875 (2008)
Sociedade Brasileira De Quimica, Quimica nova interativa - quercetina, http://qnint.sbq.org.br/qni/popup_visualizarMolecula.php?id=6NuC9uLNPgID7hAidXH8Q1lvow3lBbwociTinYJvz60jIaFjMH8EPPds5i7BO5NDxBRUmAGjRhwKEcm4mDXSQQ== (accessed 28 march 2017).
Mlcek J, Jurikova T, Skrovankova S, Sochor J, Molecules, 21 (2016)
Lima IR, Pedrosa MRG, Pereira CB, Simposio Brasileiro de Educacao Quimica, Terezina (2013).
Kowalski R, J. Food Qual., 33, 269 (2010)
Onukwuli DO, Emembolu LN, Ude CN, Aliozo SO, Menkiti MC, Egypt J. Pet., 26, 103 (2017)
Morales-Sillero A, Perez AG, Casanova L, Garcia JM, Food Chem., 237, 1216 (2017)
Wanasundara PKJPD, Shahidi F, Antioxidants: Science, technology, and applications, Wiley-Interscience, New Jersey (2005).
Franca FRM, Freitas LD, Ramos ALD, da Silva GF, Brandao ST, Fuel, 203, 627 (2017)
Kobori M, Takahashi Y, Akimoto Y, Sakurai M, Matsunaga I, Nishimuro H, Ippoushi K, Oike H, Ohnishi-Kameyama M, J. Funct. Foods, 15, 551 (2015)
van der Westhuizen I, Focke WW, Fuel, 219, 126 (2018)
Liu D, Li Y, Qian Y, Xiao Y, Du S, Qiu X, ACS Sustainable Chem. Eng., 5, 8424 (2017)
Pedrielli P, Skibsted LH, J. Agric. Food Chem., 50, 7138 (2002)
Rawat DS, Joshi G, Pandey JK, Lamba BY, Kumar P, Fuel, 214, 471 (2018)
Yin J, Becker EM, Andersen ML, Skibsted LH, Food Chem., 135, 2195 (2012)
Jia ZS, Zhou B, Yang L, Wu LM, Liu ZL, J. Chem. Soc.-Perkin Trans. 1, 2, 911 (1998)
Jesus MR, Soares TDC, Silva PRM, Romeiro GA, Fonseca MG, Batista LN, Sustainable Energy Fuels, 1, 56 (2017)

[1] Albuquerque MCG, Machado YL, Torres AEB, Azevedo DCS, Cavalcante CL, Firmiano LR, Parente EJS, Renew. Energy, 34(3), 857 (2009)

[2] Knothe G, Gerpen JV, Krajl J, The biodiesel handbook, AOCS Press, Campaign (2010).

[3] Christensen E, McCormick RL, Fuel Process. Technol., 128, 339 (2014)

[4] Simic MG, J. Chem. Educ., 58, 125 (1981)

[5] Frankel EN, Lipid oxidantion, Woodhead Publishing, Filadelfia (2012).

[6] Borsato D, Galvan D, Pereira JL, Orives JR, Angilelli KG, Coppo RL, J. Braz. Chem. Soc., 25, 1984 (2014)

[7] Maia ECR, Borsato D, Moreira I, Spacino KR, Rodrigues PRP, Gallina AL, Fuel Process. Technol., 92(9), 1750 (2011)

[8] Rawat DS, Joshi G, Lamba BY, Tiwari AK, Kumar P, Energy, 84, 643 (2015)

[9] de Sousa LS, de Moura CVR, de Oliveira JE, de Moura EM, Fuel, 134, 420 (2014)

[10] Pereira DF, Silva APD, Vasconcelos VM, Aranda DAG, Silva GFD, Rev. Tecnol., 33, 156 (2012)

[11] Huang J, Wang Y, Xie Z, Zhou Y, Zhang Y, Wan X, Eur. J. Clin. Nutr., 68, 1075 (2014)

[12] Sueth-Santiago V, Mendes-Silva GP, Decote-Ricardo D, Lima MEF, Quim. Nova, 38, 538 (2015)

[13] Gerin F, Sener U, Erman H, Yilmaz A, Aydin B, Armutcu F, Gurel A, Inflammation, 39, 700 (2016)

[14] Sfgate, Foods high in catechins, http://healthyeating.sfgate.com/foods-high-catechins-4512.html (accessed 04 april 2017).

[15] Du GJ, Zhang Z, Wen XD, Yu C, Calway T, Yuan CS, Wang CZ, Nutrients, 4 (2012)

[16] Matsubara S, Rodriguez-Amaya DB, Food Sci. Technol., 26, 401 (2006)

[17] Franca FRM, Menezes DS, Moreira JJS, Silva GF, Brandao ST, Congresso Brasileiro de Engenharia Quimica, Florianopolis, 1 (2014).

[18] Borra SK, Gurumurthy P, Mahendra J, Jayamathi KM, Cherian CN, Chand R, J. Med. Plant Res., 7, 2680 (2013)

[19] Peret-Almeida L, Naghetini CDC, Nunan EDA, Junqueira RG, Gloria MBA, Ciencia e Agrotecnologia, 32, 875 (2008)

[20] Sociedade Brasileira De Quimica, Quimica nova interativa - quercetina, http://qnint.sbq.org.br/qni/popup_visualizarMolecula.php?id=6NuC9uLNPgID7hAidXH8Q1lvow3lBbwociTinYJvz60jIaFjMH8EPPds5i7BO5NDxBRUmAGjRhwKEcm4mDXSQQ== (accessed 28 march 2017).

[21] Mlcek J, Jurikova T, Skrovankova S, Sochor J, Molecules, 21 (2016)

[22] Lima IR, Pedrosa MRG, Pereira CB, Simposio Brasileiro de Educacao Quimica, Terezina (2013).

[23] Kowalski R, J. Food Qual., 33, 269 (2010)

[24] Onukwuli DO, Emembolu LN, Ude CN, Aliozo SO, Menkiti MC, Egypt J. Pet., 26, 103 (2017)

[25] Morales-Sillero A, Perez AG, Casanova L, Garcia JM, Food Chem., 237, 1216 (2017)

[26] Wanasundara PKJPD, Shahidi F, Antioxidants: Science, technology, and applications, Wiley-Interscience, New Jersey (2005).

[27] Franca FRM, Freitas LD, Ramos ALD, da Silva GF, Brandao ST, Fuel, 203, 627 (2017)

[28] Kobori M, Takahashi Y, Akimoto Y, Sakurai M, Matsunaga I, Nishimuro H, Ippoushi K, Oike H, Ohnishi-Kameyama M, J. Funct. Foods, 15, 551 (2015)

[29] van der Westhuizen I, Focke WW, Fuel, 219, 126 (2018)

[30] Liu D, Li Y, Qian Y, Xiao Y, Du S, Qiu X, ACS Sustainable Chem. Eng., 5, 8424 (2017)

[31] Pedrielli P, Skibsted LH, J. Agric. Food Chem., 50, 7138 (2002)

[32] Rawat DS, Joshi G, Pandey JK, Lamba BY, Kumar P, Fuel, 214, 471 (2018)

[33] Yin J, Becker EM, Andersen ML, Skibsted LH, Food Chem., 135, 2195 (2012)

[34] Jia ZS, Zhou B, Yang L, Wu LM, Liu ZL, J. Chem. Soc.-Perkin Trans. 1, 2, 911 (1998)

[35] Jesus MR, Soares TDC, Silva PRM, Romeiro GA, Fonseca MG, Batista LN, Sustainable Energy Fuels, 1, 56 (2017)