최적의 프로필렌/프로판 흡착 분리 성능을 가지는 흡착제의 개발 전략들

김태훈; 이승준; 김서율; 김아름; 배윤상; Tea-Hoon Kim; Seung-Joon Lee; Seo-Yul Kim; Ah-Reum Kim; Youn-Sang Bae

Korean Chemical Engineering Research, Vol.57, No.4, 484-491, August, 2019

DOI10.9713/kcer.2019.57.4.484 Export Citation

최적의 프로필렌/프로판 흡착 분리 성능을 가지는 흡착제의 개발 전략들

Design Strategies for Adsorbents with Optimal Propylene/propane Adsorptive Separation Performances

김태훈, 이승준, 김서율, 김아름, 배윤상^†

연세대학교 화공생명공학과, 03722 서울시 서대문구 연세로 50

Tea-Hoon Kim, Seung-Joon Lee, Seo-Yul Kim, Ah-Reum Kim, and Youn-Sang Bae^†

Department of Chemical and Biomolecular Engineering, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul, 03722, Korea

E-mail:

An efficient propylene/propane separation technology is needed to obtain high-purity propylene, which is a raw material for polypropylene synthesis. Since conventional cryogenic distillation is an energy-intensive process due to the similar physicochemical properties of propylene and propane, adsorptive separation has gained considerable interest. In this study, we have computationally investigated the changes in adsorption separation performances by arbitrarily controlling the adsorption strength of open metal sites in two different types of metal-organic frameworks (MOFs). Through the evaluation of adsorptive separation performances in terms of working capacity, selectivity, and Adsorption Figure of Merit (AFM), we have suggested proper density and strength of adsorption sites as well as appropriate temperature condition to obtain optimal propylene/propane adsorptive separation performances.

Keywords:Olefin/paraffin separation;Propylene/propane separation;Grand canonical Monte Carlo (GCMC);Metal-organic framework (MOF);Adsorption

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Grande CA, Gascon J, Kapteijn F, Rodrigues AE, Chem. Eng. J., 160(1), 207 (2010)
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Furukawa H, Cordova KE, O'Keeffe M, Yaghi OM, Science, 341(6149), 123044 (2013)
Khan NA, Jhung SH, J. Hazard. Mater., 325, 198 (2017)
Lamia N, Jorge M, Granato MA, Paz FAA, Chevreau H, Rodrigues AE, Chem. Eng. Sci., 64(14), 3246 (2009)
Wuttke S, Bazin P, Vimont A, Serre A, Seo C, Hwang YK, Chang JS, Ferey G, Daturi M, Chem.-Eur. J., 18(38), 11959 (2012)
Bae YS, Lee CY, Kim KC, Farha OK, Nickias P, Hupp JT, Nguyen ST, Snurr RQ, Angew. Chem.-Int. Edit., 51(8), 1857 (2012)
Lee SJ, Bae YS, J. Phys. Chem. C, 118(34), 19833 (2014)
Bae YS, Snurr RQ, Microporous Mesoporous Mater., 132(1-2), 300 (2010)
Lee H, Choi JH, Yeo YK, Song HK, Na BK, Korean Chem. Eng. Res., 36(6), 809 (2000)
Sumer Z, Keskin S, Ind. Eng. Chem. Res., 55(39), 10404 (2016)
Dubbeldam D, Calero S, Ellis DE, Snurr RQ, Mol. Simul., 42(2), 81 (2016)
Mayo SL, Olafson BD, Goddard WA, J. Phys. Chem., 94(26), 8897 (1990)
Dubbeldam D, Calero S, Vlugt TJH, Krishna R, Maesen TLM, Smit B, J. Phys. Chem. B, 108(33), 12301 (2004)
Martin MG, Siepmann JI, J. Phys. Chem. B, 102(14), 2569 (1998)
Da Silva FA, Rodrigues AE, AlChE J., 47, 341 (2001)
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[1] Yang RT, Adsorbents: fundamentals and applications, John Wiley & Sons(2003).

[2] Jarvelin H, Fair JR, Ind. Eng. Chem. Res., 32(10), 2201 (1993)

[3] Grande CA, Gascon J, Kapteijn F, Rodrigues AE, Chem. Eng. J., 160(1), 207 (2010)

[4] Ferey G, Chem. Soc. Rev., 37(1), 191 (2008)

[5] Furukawa H, Cordova KE, O'Keeffe M, Yaghi OM, Science, 341(6149), 123044 (2013)

[6] Khan NA, Jhung SH, J. Hazard. Mater., 325, 198 (2017)

[7] Lamia N, Jorge M, Granato MA, Paz FAA, Chevreau H, Rodrigues AE, Chem. Eng. Sci., 64(14), 3246 (2009)

[8] Wuttke S, Bazin P, Vimont A, Serre A, Seo C, Hwang YK, Chang JS, Ferey G, Daturi M, Chem.-Eur. J., 18(38), 11959 (2012)

[9] Bae YS, Lee CY, Kim KC, Farha OK, Nickias P, Hupp JT, Nguyen ST, Snurr RQ, Angew. Chem.-Int. Edit., 51(8), 1857 (2012)

[10] Lee SJ, Bae YS, J. Phys. Chem. C, 118(34), 19833 (2014)

[11] Bae YS, Snurr RQ, Microporous Mesoporous Mater., 132(1-2), 300 (2010)

[12] Lee H, Choi JH, Yeo YK, Song HK, Na BK, Korean Chem. Eng. Res., 36(6), 809 (2000)

[13] Sumer Z, Keskin S, Ind. Eng. Chem. Res., 55(39), 10404 (2016)

[14] Dubbeldam D, Calero S, Ellis DE, Snurr RQ, Mol. Simul., 42(2), 81 (2016)

[15] Mayo SL, Olafson BD, Goddard WA, J. Phys. Chem., 94(26), 8897 (1990)

[16] Dubbeldam D, Calero S, Vlugt TJH, Krishna R, Maesen TLM, Smit B, J. Phys. Chem. B, 108(33), 12301 (2004)

[17] Martin MG, Siepmann JI, J. Phys. Chem. B, 102(14), 2569 (1998)

[18] Da Silva FA, Rodrigues AE, AlChE J., 47, 341 (2001)

[19] Yazaydin AO, Snurr RQ, Park TH, Koh K, Liu J, et al., J. Am. Chem. Soc., 131(51), 18198 (2009)