Electrochemical Performance of High-Voltage LiMn0.8Fe0.2PO4 Cathode with Polyacrylonitrile (PAN)-Based Gel Polymer Electrolyte

O. Hyeon Kwon; Jae-Kwang Kim

Korean Chemical Engineering Research, Vol.57, No.4, 547-552, August, 2019

DOI10.9713/kcer.2019.57.4.547 Export Citation

Electrochemical Performance of High-Voltage LiMn0.8Fe0.2PO4 Cathode with Polyacrylonitrile (PAN)-Based Gel Polymer Electrolyte

O. Hyeon Kwon, and Jae-Kwang Kim^†

Department of Solar & Energy Engineering, Cheongju University, 298, Daeseong-ro, Cheongwon-gu, Cheongju-si, Chungcheongbuk-do, 28503, Korea

E-mail:

Electrochemical properties of LiMn0.8Fe0.2PO4 cathode were investigated with gel polymer electrolyte (GPE). To access fast and efficient transport of ions and electrons during the charge/discharge process, a pure and well-crystallized LiMn0.8Fe0.2PO4 cathode material was directly synthesized via spray-pyrolysis method. For high operation voltage, polyacrylonitrile (PAN)-based gel polymer electrolyte was then prepared by electrospinning process. The gel polymer electrolyte showed high ionic conductivity of 2.9 × 10-3 S cm-1 at 25 °C and good electrochemical stability. Li/GEP/ LiMn0.8Fe0.2PO4 cell delivered a discharge capacity of 159 mAh g-1 at 0.1 C rate that was close to the theoretical value (170 mAh g-1). The cell allows stable cycle performance (99.3% capacity retention) with discharge capacity of 133.5 mAh g-1 for over 300 cycles at 1 C rate and exhibits high rate-capability. PAN-based gel polymer is a suitable electrolyte for application in LiMn0.8Fe0.2PO4/Li batteries with perspective in high energy density and safety.

Keywords:LiMn0.8Fe0.2PO4;Polyacrylonitrile;High potential;Electrochemical performance;Lithium ion battery

[References]

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[4] Chung SY, Bloking JT, Chiang YM, Nature, 1(2), 123 (2002)

[5] Huang YH, Goodenough JB, Chem. Mater., 20(23), 7237 (2008)

[6] Kang B, Ceder G, Nature, 458, 190 (2009)

[7] Tarascon JM, Armand M, Nature, 414, 359 (2001)

[8] Zane D, Carewska M, Scaccia S, Cardellini F, Prosini PP, Electrochim. Acta, 49(25), 4259 (2004)

[9] Wang L, Zhou F, Ceder G, Electrochem. Solid State Lett., 11(6), A94 (2008)

[10] Drezen T, Kwon NH, Bowen P, Teerlinck I, Isono M, Exnar I, J. Power Sources, 174(2), 949 (2007)

[11] Martha SK, Markovsky B, Grinblat J, Gofer Y, Haik O, Zinigrad E, Aurbach D, Drezen T, Wang D, Deghenghi G, Exnar I, J. Electrochem. Soc., 156(7), A541 (2009)

[12] Choi D, Wang D, Bae IT, Xiao J, Nie Z, Wang W, Yang Z, Nano Lett., 10(8), 2799 (2010)

[13] Bakenov Z, Taniguchi I, J. Power Sources, 195(21), 7445 (2010)

[14] Kang B, Ceder G, J. Electrochem. Soc., 157(7), A808 (2010)

[15] Yonemura M, Yamada A, Takei Y, Sonoyama N, Kanno R, J. Electrochem. Soc., 151(9), A1352 (2004)

[16] Zhou F, Cococcioni M, Marianetti CA, Morgan D, Ceder G, Physical Review B, 70(23), 235121 (2004)

[17] Yamada A, Hosoya M, Chung SC, Kudo Y, Hinokuma K, Liu KY, Nishi Y, J. Power Sources, 119-121, 232 (2003)

[18] Yan SY, Wang CY, Gu RM, Sun S, Li MW, J. Alloy. Compd., 628, 471 (2015)

[19] Li GH, Azuma H, Tohda M, J. Electrochem. Soc., 149(6), A743 (2002)

[20] Mi CH, Zhang XH, Zhao XB, Li HL, Mater. Sci. Eng. B-Solid State Mater. Adv. Technol., 129(1-3), 8 (2006)

[21] Hong JA, Wang F, Wang XL, Graetz J, J. Power Sources, 196(7), 3659 (2011)

[22] Hu C, Yi H, Fang H, Yang B, Yao Y, Ma W, Dai Y, Electrochem. Commun., 12, 1784 (2010)

[23] Kim JK, Hwang GC, Kim SH, Ahn JH, J. Ind. Eng. Chem., 66, 94 (2018)

[24] Yamada A, Kudo Y, Liu KY, J. Electrochem. Soc., 148(10), A1153 (2001)

[25] Yamada A, Chung SC, J. Electrochem. Soc., 148(8), A960 (2001)

[26] Abbrent S, Plestil J, Hlavata D, Lindgren J, Tegenfeldt J, Wendsjo A, Polymer, 42(4), 1407 (2001)

[27] Huang BY, Wang ZX, Chen LQ, Xue RJ, Wang FS, Solid State Ion., 91(3-4), 279 (1996)

[28] Raghavan P, Manuel J, Zhao X, Kim DS, Ahn JH, Nah C, J. Power Sources, 196(16), 6742 (2011)

[29] Tsutsumi H, Matsuo A, Takase K, Doi S, Hisanaga A, Onimura K, Oishi T, J. Power Sources, 90(1), 33 (2000)

[30] Jo MS, Ghosh S, Jeong SM, Kang YC, Cho JS, Nano-Micro Lett., 11(1), 1 (2019)

[31] Oh SH, Kim JK, Kang YC, Cho JS, Nanoscale, 10(39), 18734 (2018)

[32] Ko HS, Park HW, Kim GJ, Lee JD, Korean J. Chem. Eng., 36(4), 620 (2019)

[33] Wang Y, He P, Zhou H, Energy Environ. Sci., 4(3), 805 (2011)

[34] Raghaven P, Choi JW, Ahn JH, Cheruvally G, Chauhan GS, Ahn HJ, Nah C, J. Power Sources, 184(2), 437 (2008)

[35] Min HS, Ko JM, Kim DW, J. Power Sources, 119, 469 (2003)

[36] Abraham KM, Jiang Z, Carroll B, Chem. Mater., 9(9), 1978 (1997)

[37] Watanabe M, Sanui K, Ogata N, Kobayashi T, Ohtaki Z, J. Appl. Phys., 57, 123 (1985)

[38] Roberts MR, Vitins G, Denuault G, Owen JR, J. Electrochem. Soc., 157(4), A381 (2010)