Transformation of pore and fracture structure of coals with supercritical CO2 (scCO(2)) -H2O is a key to CO2 injection and CH4 production efficiencies during the CO2 enhanced coalbed methane process. To study the transformation of pores and fractures in the coals with CO2, two reservoir conditions, which simulate1000m (45 degrees C, 10 MPa) and 2000 m (80 degrees C, 20 MPa) depths, are applied to four types of high metamorphic coals from Qinshui Basin to study the influences of temperature and pressure on pore volume and pore sized distribution change. Nuclear magnetic resonance, high pressure mercury intrusion, X-ray CT scanning and permeability experiments are performed and the effects of scCO(2) on coal permeability and the influencing factors are discussed. The results show that scCO(2)-H2O has a positive effect on the improvement on the pore fracture system. It could add or expand pores and fractures, leading to the increase in pore number, porosity, pore volume, pore specific surface area, connected pore volume, and pore throat number. And then, increased the permeability which had a positive correlation with the experimental temperature and pressure. The growth of permeability could be as high as 114.10 times, and it was higher in horizontal to bedding direction than that of the vertical to bedding direction. Coal expansion could lead to the addition and enlargement of micro-fractures and enhance the connectivity between seepage pores and fractures. Mineral dissolution could lead to the formation of a large number of effectively connected and non-effectively connected pores, especially the latter, which was positively correlated with simulated temperature and pressure. In addition, the effectively connected pores tend to develop in vertical original micro-fractures. Moreover, the more complete the reaction is, the more favorable it is to increase the pore volume of fractures.