International Journal of Hydrogen Energy, Vol.44, No.25, 12715-12723, 2019
Hydrogen storage potential in MIL-101 at 200 K
Hydrogen adsorption isotherms for MIL-101 metal-organic framework are reported within a wide pressure range for temperatures between 77 and 295 K. Data modeling with the modified Dubinin-Astakhov equation shows a good fitting with the experimental results. The calculated absolute adsorption allowed the evaluation of the total hydrogen storage capacity for high pressure storage tank filled with MIL-101 as sorbent. The results show that the gravimetric and volumetric storage capacities at 198 K and 70 MPa are within the presentday accepted DOE targets, even if the storage capacity is slightly decreased by 3-6% as compared to the tank without sorbent. Moreover, the calculations reveal that the dormancy time is much increased, as compared to a tank without sorbent, exceeding the ultimate DOE target of 14 days. The MIL-101 assisted cold high-pressure hydrogen storage at -200 K and 70 MPa, brings about an additional advantage and seems promising for both mobile and stationary applications. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
Keywords:Cold hydrogen storage;High pressure adsorption isotherms;MIL-101;Absolute adsorption;Dormancy;DOE target