International Journal of Hydrogen Energy, Vol.44, No.24, 12399-12408, 2019
Self-doped Sargassum spp. derived biocarbon as electrocatalysts for ORR in alkaline media
In this work, high surface area N-doped carbon synthesis from Sargassum spp. is reported as a low cost alternative for electrocatalysts production for the oxygen reduction reaction (ORR). First, Sargassum spp. was activated with potassium hydroxide (SKPH) and then doped with hydrazine (SKPHD). As a result of the activation process, SKPH obtained a high surface area (2289 m(2) g(-1)), 0.16% nitrogen and 2.63% sulfur content; it also showed four-electron-transfer mechanism when tested as electrocatalyst in alkaline medium. Besides, SKPHD presented 3.60% nitrogen content in the bulk and higher ORR activity (0.838 V onset potential vs. RHE and 4.59 mA cm(-2) current density) very close to 20% Pt/C (5.25 mA cm(-2)). Results indicate that using seaweeds as a synthesis precursor is an alternative for the Sargassum spp. disposal in the Caribbean due to its high availability and efficiency towards ORR. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.