화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.78, 90-96, October, 2019
DOI10.1016/j.jiec.2019.06.035  Export Citation
Optimization of photocatalytic degradation of Cefradine using a “green” goethite/H2O2 system
Ruiping Li, Shaoming Hong, Xiaocong Li1, Bin Zhang, Hailin Tian, and Yingping Huang†
  • Engineering Research Center of Eco-environment in Three Gorges Reservoir Region, Ministry of Education, China Three Gorges University, Yichang 443002, China
  • 1Yichang Humanwell Pharmaceutical Co.,Ltd, Yichang 443005, China
E-mail:
An environmental friendly photocatalyst, goethite in the presence of H2O2, was used to remove Cefradine from aqueous solution. Four factors were examined using Box-Behnken Design and results were analyzed by response surface method. H2O2 concentration had the largest effect on Cefradine removal and the optimal reaction conditions were: H2O2 concentration, 4 mmol/L; solution pH, 5; goethite dosage, 1.2 g/L and illumination time, 9 h. Experimental data on Cefradine removal under optimal conditions closely coincided with model predictions, validating the model. Hydroxyl radicals (·OH) and superoxide anion were involved in the Cefradine photodegradation process and that ·OH makes the larger contribution.
Keywords:Goethite;Cefradine;Photocatalytic degradation;Response surface methodology;Box.Behnken Design
  1. Fernandes R, Amador P, Prudencio C, Rev. Med. Microbiol., 24, 7 (2013)
  2. Ribeiro AR, Sures B, Schmidt TC, Environ. Pollut., 241, 1153 (2018)
  3. Cardoso O, Porcher JM, Sanchez W, Chemosphere, 115, 20 (2014)
  4. Gilbert N, Nature, 481(7380), 125 (2012)
  5. Zhang J, Meng J, Li Y, Hu C, Arch. Pharm., 343, 553 (2010)
  6. Guo R, Xie W, Chen J, Food Chem. Toxicol., 78, 116 (2015)
  7. Wang XH, Lin AY, Environ. Sci. Technol., 46, 12417 (2012)
  8. Ribeiro AR, Sures B, Schmidt TC, Sci. Total Environ., 619-620, 866 (2018)
  9. Nature 492, 314 (2012).
  10. Knapp CW, Dolfing J, Ehlert PAI, Graham DW, Environ. Sci. Technol., 44, 580 (2010)
  11. Cha J, Carlson KH, Sci. Total Environ., 640-641, 1346 (2018)
  12. Li LP, Wei DB, Wei GH, Du YG, J. Hazard. Mater., 262, 48 (2013)
  13. Dodd MC, Rentsch D, Singer HP, Kohler HPE, Gunten U, Environ. Sci. Technol., 44, 5940 (2010)
  14. Navalon S, Alvaro M, Garcia H, Water Res., 42, 1935 (2008)
  15. Li L, Wei D, Wei G, Du Y, Chemosphere, 149, 279 (2016)
  16. Karlesa A, De Vera GAD, Dodd MC, Park J, Espino MPB, Lee Y, Environ. Sci. Technol., 48, 10380 (2014)
  17. Zhang K, Zhou X, Du P, Zhang T, Cai M, Sun P, Huang CH, Water Res., 123, 153 (2017)
  18. Peterson JW, O’Meara TA, Seymour MD, Wang W, Gu B, Environ. Pollut., 157, 1849 (2009)
  19. Fakhri A, Adami S, J. Taiwan Inst. Chem. Eng., 45, 1001 (2014)
  20. Liu H, Liu WF, Zhang JA, Zhang CL, Ren LA, Li Y, J. Hazard. Mater., 185(2-3), 1528 (2011)
  21. Fabbri D, Minella M, Maurino V, Minero C, Vione D, Chemosphere, 134, 452 (2015)
  22. He X, Mezyk SP, Michael I, Fatta-Kassinos D, Dionysiou DD, J. Hazard. Mater., 279, 375 (2014)
  23. Serna-Galvis EA, Ferraro F, Silva-Agredo J, Torres-Palma RA, Water Res., 122, 128 (2017)
  24. Shooshtari NM, Ghazi MM, Chem. Eng. J., 315, 527 (2017)
  25. Chen J, Shu J, Anqi Z, Juyuan H, Yan Z, Chen J, Diam. Relat. Mater., 70, 137 (2016)
  26. Bansal P, Verma A, J. Photochem. Photobiol. A-Chem., 342, 131 (2017)
  27. Anandan S, Pugazhenthiran N, Lee GJ, Wu JJ, J. Mol. Catal. A-Chem., 379, 112 (2013)
  28. Gurkan YY, Turkten N, Hatipoglu A, Cinar Z, Chem. Eng. J., 184, 113 (2012)
  29. Xiao Y, Song X, Liu Z, Li R, Zhao X, Huang Y, J. Ind. Eng. Chem., 45, 248 (2017)
  30. Gadipelly C, Perez-Gonzalez A, Yadav GD, Ortiz I, Ibanez R, Rathod VK, Marathe KV, Ind. Eng. Chem. Res., 53(29), 11571 (2014)
  31. Wang N, Zheng T, Zhang G, Wang P, J. Environ. Chem. Eng., 4, 762 (2016)
  32. Boczkaj G, Fernandes A, Chem. Eng. J., 320, 608 (2017)
  33. Liu H, Chen T, Frost RL, Chemosphere, 103, 1 (2014)
  34. He J, Yang X, Men B, Wang D, J. Environ. Sci., 39, 97 (2016)
  35. Wang Y, Gao YW, Chen L, Zhang H, Catal. Today, 252, 107 (2015)
  36. Li XY, Huang Y, Li C, Shen JM, Deng Y, Chem. Eng. J., 260, 28 (2015)
  37. Chen R, Yang L, Guo Y, Zheng W, Liu H, Wei Y, J. Photochem. Photobiol. A-Chem., 353, 337 (2018)
  38. Benacherine M, Debbache N, Ghoul I, Mameri Y, J. Photochem. Photobiol. A-Chem., 335, 70 (2017)
  39. Mameri Y, Debbache N, Benacherine M, Seraghni N, Sehili T, J. Photochem. Photobiol. A-Chem., 315, 129 (2016)
  40. Garrido-Ramirez EG, Theng BKG, Mora ML, Appl. Clay Sci., 47, 182 (2010)
  41. Ding Y, Zheng J, Xia X, Ren T, Kan J, Food Sci. Technol., 67, 206 (2016)
  42. Ai CL, Zhou DD, Wang Q, Shao XW, Lei YJ, Sol. Energy, 113, 34 (2015)
  43. Gupta VK, Agarwal S, Asif M, Fakhri A, Sadeghi N, J. Colloid Interface Sci., 497, 193 (2017)
  44. Caprile KA, J. Vet. Pharmacol. Ther., 11, 1 (1988)
  45. Chen JQ, Guo RX, J. Hazard. Mater., 209-210, 520 (2012)
  46. Ge M, Zhu N, Zhao YP, Li J, Liu L, Ind. Eng. Chem. Res., 51(14), 5167 (2012)
  47. Wang SL, Wang LL, Ma WH, Johnson DM, Fang YF, Jia MK, Huang YP, Chem. Eng. J., 259, 410 (2015)
  48. Ooi TY, Yong EL, Din MFM, Rezania S, Aminudin E, Chelliapan S, Rahman AA, Park J, J. Environ. Manage., 228, 13 (2018)
  49. Bahrami H, Eslami A, Nabizadeh R, Mohseni-Bandpi A, Asadi A, Sillanpaa M, J. Clean Prod., 198, 1210 (2018)
  50. Iurascu B, Siminiceanu I, Vione D, Vicente MA, Gil A, WaterRes., 43, 1313 (2009)
  51. Duan HT, Liu Y, Yin XH, Bai JF, Qi J, Chem. Eng. J., 283, 873 (2016)
  52. Miyauchi M, Phys. Chem. Chem. Phys., 10, 6258 (2008)