화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.78, 198-209, October, 2019
DOI10.1016/j.jiec.2019.06.013  Export Citation
Coupling membrane and Fe-Pd bimetallic nanoparticles for trichloroethene removing from water
Bangkai Li1, 2, Xi Chen1, 2, †, Kun Li1, 2, Chenghao Zhang1, 2, Yang He1, 2, Runhong Du1, 2, Jianzu Wang1, 2, and Li Chen1, 2
  • 1State Key Laboratory of Hollow Fiber Membrane Materials and Processes, Tianjin Polytechnic University, Tianjin 300387, PR China
  • 2School of Materials Science and Engineering, Tianjin Polytechnic University, Tianjin 300387, PR China
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A novel composite membrane with membrane pores loading acrylic acid microgels coated by Fe.Pd bimetallic nanoparticles (NPs) was prepared for the dechlorination of trichloroethene (TCE) in water. This membrane was prepared by firstly immobilizing acrylic acid microgels in poly (vinylidene fluoride) (PVDF) membrane pores and then in-situ synthesis of Fe-Pd bimetallic nanoparticles (NPs). The Fe-Pd NPs coupled with the porous membranes enabled dechlorination to be conducted in a cross-flow model including a penetrative flow and a tangential flow. In such a model, a large number of dechlorination occurred in penetrative flow fluid while no dechlorination occurred in tangential flow fluid. Thus, products and reactants are always timely isolated in the cross-flow dechlorination process. The composite membrane prevents Fe-Pd NPs from contamination because its nanosize surface pores stop colloids and bovine serum albumin (BSA) from entering into the membrane interior. However, these small surfaces pores cannot slow the diffusion of reactants into membrane pores, and thus make the asformed composite membrane also show a fast dechlorination rate in a batch reaction. All in all, TCE dechlorination by the composite membrane shows many advantages including the fast dechlorination rate, the convenient operation, the timely isolation of products from reactants, and the ignorable extra steps for separation of metal NPs.
Keywords:Composite membrane;Fe-Pd nanoparticle;Trichloroethylene;Dechlorination;Microgel
  1. Zhang X, Gu XG, Lu SG, Brusseau ML, Xu MH, Fu XR, Qiu ZF, Sui Q, Chem. Eng. J., 325, 188 (2017)
  2. Li SJ, Fang YL, Romanczuk CD, Jin ZH, Li TL, Wong MS, Appl. Catal. B: Environ., 125, 95 (2012)
  3. Han YL, Liu CJ, Horita J, Yan WL, Appl. Catal. B: Environ., 188, 77 (2016)
  4. Wang JQ, Ng CK, Cao B, Qing WH, Liu F, Tang CYY, Appl. Catal. A: Gen., 559, 122 (2018)
  5. Verce MF, Madrid VM, Gregory SD, Demir Z, Singleton MJ, Salazar EP, Jackson PJ, Halden RU, Verce A, Bioremediat. J., 19, 18 (2015)
  6. Verdini R, Aulenta F, de Tora F, Lai A, Majone M, Chemosphere, 136, 72 (2015)
  7. Fu F, Dionysiou DD, Liu H, Chem. Eng. J., 267, 194 (2014)
  8. Audi-Miro C, Cretnik S, Torrento C, Rosell M, Shouakar-Stash O, Otero N, Palau J, Elsner M, Soler A, J. Hazard. Mater., 299, 747 (2015)
  9. Bhattacharjee S, Ghoshal S, Environ. Sci. Technol., 50, 8631 (2016)
  10. Hernandez S, Papp JK, Bhattacharyya D, Ind. Eng. Chem. Res., 53(3), 1130 (2014)
  11. Wan HY, Briot NJ, Saad A, Ormsbee L, Bhattacharyya D, J. Membr. Sci., 530, 147 (2017)
  12. Zhao X, Lv L, Pan BC, Zhang WM, Zhang SJ, Zhang QX, Chem. Eng. J., 170(2-3), 381 (2011)
  13. Liu WJ, Qian TT, Jiang H, Chem. Eng. J., 236, 448 (2014)
  14. Wang XY, Chen C, Liu HL, Ma J, Water Res., 42, 4656 (2008)
  15. Hernandez S, Lei S, Rong W, Bhattacharyya D, ACS Sustain. Chem. Eng., 4, 907 (2016)
  16. Smuleac V, Varma R, Sikdar S, Bhattacharyya D, J. Membr. Sci., 379(1-2), 131 (2011)
  17. He F, Zhao DY, Appl. Catal. B: Environ., 84(3-4), 533 (2008)
  18. Gao Y, Wang FF, Wu Y, Naidu R, Chen ZL, Chem. Eng. J., 285, 459 (2016)
  19. Smuleac V, Bachas L, Bhattacharyya D, J. Membr. Sci., 346(2), 310 (2010)
  20. Dumee LF, Maina JW, Merenda A, Reis R, He L, Kong LX, J. Membr. Sci., 528, 217 (2017)
  21. Wu L, Ritchie SMC, Environ. Prog., 27, 218 (2008)
  22. Dumee LF, He L, King PC, Le Moing M, Guller I, Duke M, Hodgson PD, Gray S, Poole AJ, Kong LX, J. Membr. Sci., 475, 552 (2015)
  23. Crock CA, Tarabara VV, Enviro. Sci. Nano, 3, 453 (2016)
  24. He Y, Chen X, Bi S, Shi C, Chen L, Li L, Polym. Adv. Technol., 24, 934 (2013)
  25. Chen X, He Y, Shi CC, Fu WG, Bi SY, Wang ZY, Chen L, J. Membr. Sci., 469, 447 (2014)
  26. Chen X, Zhao BW, Han P, Fu WG, Chen L, React. Funct. Polym., 84, 10 (2014)
  27. Chen X, Zhao B, Zhao L, Bi S, Han P, Feng X, Chen L, RSC Adv., 4, 29933 (2014)
  28. Parnian MJ, Rowshanzamir S, Prasad AK, Advani SG, J. Membr. Sci., 565, 342 (2018)
  29. Li S, Liu S, Huang F, Lin S, Zhang H, Cao S, Chen L, He Z, Lutes R, Yang J, Ni Y, Huang L, ACS Sustain. Chem. Eng., 6, 13168 (2018)
  30. Huang R, Wu M, Zhang T, Li D, Tang P, Feng Y, ACS Sustain. Chem. Eng., 5, 2774 (2017)
  31. Xu J, Bhattacharyya D, Ind. Eng. Chem. Res., 46(8), 2348 (2007)
  32. Lai B, Zhang YH, Chen ZY, Yang P, Zhou YX, Wang JL, Appl. Catal. B: Environ., 144, 816 (2014)
  33. Xia Z, Liu H, Wang S, Meng Z, Ren N, Chem. Eng. J., 200-202, 214 (2012)
  34. Muftikian R, Nebesny K, Fernando Q, Korte N, Environ. Sci. Technol., 30, 3593 (1996)
  35. Kidambi S, Bruening ML, Chem. Mater., 17, 301 (2005)
  36. Liu YQ, Choi H, Dionysiou D, Lowry GV, Chem. Mater., 17, 5315 (2005)
  37. Kausamo A, Andersin J, Honkala K, J. Phys. Chem. C., 118, 19759 (2014)
  38. Bi S, Chen X, Fu WG, Chen L, Sheng HY, Yang Q, Polym.Compos., 35, 2251 (2014)
  39. Dotzauer DA, Bhattacharjee S, Wen Y, Bruening ML, Langmuir, 25(3), 1865 (2009)
  40. Westermann T, Melin T, Chem. Eng. Process., 48(1), 17 (2009)