화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.78, 372-382, October, 2019
DOI10.1016/j.jiec.2019.05.032  Export Citation
Catalytic cracking of raw bio-oil under FCC unit conditions over different zeolite-based catalysts
Álvaro Ibarra, Idoia Hita†, Miren J. Azkoiti, José M. Arandes, and Javier Bilbao
  • Chemical Engineering Department, University of the Basque Country (UPV/EHU), P. O. Box 644, 48080 Bilbao, Spain
E-mail:
The performance of different zeolite-based catalysts (HY, HZSM-5 and HBeta) on the catalytic cracking of bio-oil has been explored, using a simulated riser reactor and resembling industrial FCC conditions. The effect of the C/O (catalyst/bio-oil) ratio and the zeolite types have been assessed. The level of deoxygenation is >61% (increasing with C/O ratio). Total hydrocarbon yield was higher for the HBeta catalyst (56 wt%), while the liquid hydrocarbons yields were relatively similar for all catalysts, obtaining higher gasoline yields with the HY catalyst (46-55 wt%), and higher LPG yields with the HZSM-5 catalyst (12-14 wt%) due to its higher acidity. The HY zeolite produced more coke (4-7 wt%) given its capacity for retaining coke precursors within its micropores.
Keywords:Raw bio-oil;FCC;Catalytic cracking;Zeolite;Gasoline;Deoxygenation
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