화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Chemical Engineering Research, Vol.57, No.5, 596-605, October, 2019
DOI10.9713/kcer.2019.57.5.596  Export Citation
프로톤 전도성 세라믹 멤브레인 촉매 반응기를 이용한 수소 분리 및 제조 기술
Hydrogen Separation and Production using Proton-Conducting Ceramic Membrane Catalytic Reactors
서민혜1, 2, 박은덕2, 3, †
  • 1고등기술연구원 플랜트엔지니어링센터, 17180 경기도 용인시 처인구 백암면 고안로 51번길 175-28
  • 2아주대학교 에너지시스템학부, 16499 경기도 수원시 영통구 월드컵로 206
  • 3아주대학교 화학공학과, 16499 경기도 수원시 영통구 월드컵로 206
Minhye Seo1, 2, and Eun Duck Park2, 3, †
  • 1Plant Engineering Division, Institute for Advanced Engineering, 175-28, Goan-ro 51beon-gil, Baegam-myeon, Cheoin-gu, Yongin 17180, Korea
  • 2Department of Energy Systems Research, Ajou University, 206, World cup-ro, Yeongtong-gu, Suwon-si, Gyeonggi-do, 16499, Korea
  • 3Department of Chemical Engineering, Ajou University, 206, World cup-ro, Yeongtong-gu, Suwon-si, Gyeonggi-do, 16499, Korea
E-mail:
초록
프로톤 전도성 세라믹인 페로브스카이트 구조의 산화물은 고온 환경에서 고체 전해질 및 촉매로써 동시에 활용이 가능하여, 반응과 분리기능을 동시에 갖춘 멤브레인 반응기로 적용하기에 우수한 소재이다. 특히 수소 제조 촉매와 분리, 이를 결합한 멤브레인 반응기 개발에 관한 연구는 전해질 내 도핑 금속의 종류 및 온도, 반응물의 조성 등에 따라 다양한 연구 결과가 제시되고 있다. 이에 본 총설에서는 프로톤 전도성 세라믹반응기에서 메탄을 활용하여 수소 제조촉매와 멤브레인 반응기로 응용해 온 연구 동향을 살펴보고, 차세대 수소의 제조와 분리 기술로서의 응용분야 및 전망에 관해 고찰하고자 한다.
Proton-conducting perovskite ceramic materials are highly promising for solid electrolytes as well as catalysts at high temperatures. Therefore, they possess an outstanding potential for the membrane reactor in which both reaction and separation occur at a same time. Especially, in the case of hydrogen production catalyst, hydrogen separation, and the membrane reactor coupled with catalyst and separation, extensive results have been reported on the effect of the dopant in the solid electrolytes, temperature, and composition of reactants on the performance. In this review, the recent research trend on the application of proton-conducting ceramic materials to hydrogen production catalyst, hydrogen separation, and membrane reactor is surveyed. Moreover, the potential application and prospect of these materials to the next-generation hydrogen production and separation is discussed.
Keywords:Proton-conducting ceramics;Perovskite;Hydrogen separation;Membrane;Catalytic membrane reactor
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