화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.79, 295-306, November, 2019
Shear resistance performance of low elastic polymer microspheres used for conformance control treatment
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Low elastic polymer microsphere (L-EPM) has been proposed as a functional polymer microsphere these years. L-EMP has the excellent deformation ability in the porous medium due to the low storage modulus. Herein, one kind of L-EPM with storage modulus (G') of 23.6 Pa was prepared by inverse suspension polymerization. The shear resistance of L-EPM was researched by using core flooding experiment and high shear rate emulsifier. The conformance control behavior of L-EPM was investigated by using double parallel sandpack flooding experiment. The results showed that L-EPM was a kind of swollen particle gel with three-dimensional net structure and contained amide, carboxyl, and sulfonate groups. The mechanism of water swelling property was mainly due to the formation of hydrogen bonds, hydrolysis of hydrophilic groups and the diffusion caused by osmotic pressure difference. Compared with high elastic polymer microspheres (H-EPM) and low elastic preformed particle gel (L-PPG), L-EPM had better shear resistance in the porous medium and the well casing perforation. In addition, the critical shear points of L-EPM was proposed in this work. Due to the better shear resistance and deformation ability, the conformance control behavior of L-EPM showed that L-EPM was a promising conformance control agent in the heterogeneous reservoirs.
  1. You Q, Wen Q, Fang J, Guo M, Zhang Q, Dai C, J. Pet. Sci. Technol., 174, 747 (2019)
  2. Zhang Y, Gao MW, You Q, Fan HF, Li WH, Liu YF, Fang JC, Zhao G, Jin ZH, Dai CL, Fuel, 241, 442 (2019)
  3. Lake LW, Enhanced Oil Recovery, Prentice Hall, 1989.
  4. Zhu DY, Bai BJ, Hou JR, Energy Fuels, 31(12), 13063 (2017)
  5. Li GH, Zhang GC, Wang L, Energy Fuels, 27(11), 6632 (2013)
  6. Chen LF, Zhang GC, Ge JJ, Jiang P, Zhu XM, Ran YL, Han SX, Energy Fuels, 29(11), 7196 (2015)
  7. Pu W, Zhao S, Wang S, Wei B, Yuan C, Li Y, Colloids Surf. A: Physicochem. Eng. Asp., 540, 265 (2018)
  8. Yao C, Lei G, Cathles LM, Steenhuis TS, Environ. Sci. Technol., 48, 5329 (2014)
  9. Al-Ibadi A, Civan F, SPE Prod. Oper., 28, 387 (2013)
  10. Wang LZ, Long YF, Bai BJ, Chem. Eng. J., 334, 2558 (2018)
  11. Wang LZ, Long YF, Ding HF, Geng JM, Bai BJ, Chem. Eng. J., 317, 952 (2017)
  12. Lashari ZA, Yang H, Zhu Z, Tang X, Cao C, Iqbal MW, Kang W, J. Mol. Liq., 263, 118 (2018)
  13. Pu JY, Zhou J, Chen YS, Bai BJ, Energy Fuels, 31(12), 13600 (2017)
  14. Jia H, Pu WF, Zhao JZ, Liao R, Energy Fuels, 25, 727 (2011)
  15. Chen LF, Wang JJ, Yu L, Zhang Q, Fu ML, Zhao ZC, Zu JQ, Energy Fuels, 32(6), 6650 (2018)
  16. Dai S, Chen Z, Huang Z, Russ. J. Appl. Chem., 90, 310 (2017)
  17. Hongbin Y, Wanli K, Jian Z, Bin Z, Colloids Surf. A: Physicochem. Eng. Asp., 487, 240 (2015)
  18. Pu WF, Liu R, Wang KY, Li KX, Yan ZP, Li B, Zhao L, Ind. Eng. Chem. Res., 54(3), 798 (2015)
  19. Tang X, Yang H, Gao Y, Lashari ZA, Cao C, Kang W, Colloids Surf. A: Physicochem. Eng. Asp., 547, 8 (2018)
  20. Tao SY, Ding YZ, Jiang L, Li GT, J. Colloid Interface Sci., 492, 73 (2017)
  21. Yang H, Kang W, Wu H, Yu Y, Zhu Z, Wang P, Zhang X, Sarsenbekuly B, RSC Adv., 7, 8118 (2017)
  22. Yang HB, Kang WL, Yin X, Tang XC, Song SY, Lashari ZA, Bai BJ, Sarsenbekuly B, Powder Technol., 313, 191 (2017)
  23. Zhang P, Bai S, You Q, Ji W, Yu H, Li D, Polym. Int., 66, 1312 (2017)
  24. Zhu DY, Hou JR, Chen YG, Zhao SD, Bai BJ, Energy Fuels, 32(3), 3312 (2018)
  25. Jia H, Ren Q, Pu WF, Zhao JZ, Energy Fuels, 28(11), 6735 (2014)
  26. Lopez P, Omari A, Chauveteau G, Colloids Surf. A: Physicochem. Eng. Asp., 240, 1 (2004)
  27. Omari A, Tabary R, Rousseau D, Calderon FL, Monteil J, Chauveteau G, J. Colloid Interface Sci., 302(2), 537 (2006)
  28. Yang CC, Yue XA, Li CY, Xu R, Wei JM, J. Nat. Gas Sci. Eng., 42, 56 (2017)
  29. Hu L, Bai B, Kang W, Ji Y, Fan H, Yang R, Fan X, J. Dispersion Sci. Technol., 37, 345 (2015)
  30. Kang WL, Hu LL, Zhang XF, Yang RM, Fan HM, Geng J, Pet. Sci., 12, 483 (2015)
  31. Lin M, Zhang G, Hua Z, Zhao Q, Sun F, Colloids Surf. A: Physicochem. Eng. Asp., 477, 49 (2015)
  32. Yao CJ, Lei GL, Hou J, Xu XH, Wang D, Steenhuis TS, Ind. Eng. Chem. Res., 54(43), 10925 (2015)
  33. Zhao S, Pu WF, Wei B, Xu XG, Fuel, 235, 249 (2019)
  34. Yao CJ, Wang D, Wang J, Hou J, Lei GL, Steenhuis TS, Ind. Eng. Chem. Res., 56(28), 8158 (2017)
  35. Yang H, Kang W, Tang X, Gao Y, Zhu Z, Wang P, Zhang X, J. Dispersion Sci. Technol., 39, 1808 (2018)
  36. Yang H, Kang W, Liu S, Bai B, Zhao J, Zhang B, J. Dispersion Sci. Technol., 36, 1673 (2015)
  37. Sang Q, Li YJ, Yu L, Li ZQ, Dong MZ, Fuel, 136, 295 (2014)
  38. Inomata H, Wada N, Yagi Y, Goto S, Saito S, Polymer, 36(4), 875 (1995)
  39. Liu Y, Huglin MB, Polymer, 36(8), 1715 (1995)