화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.79, 465-472, November, 2019
DOI10.1016/j.jiec.2019.07.022  Export Citation
The textural and chemical changes in ACFs with E-beam and their influence on the detection of nerve agent simulant gases
Min-Ji Kim1, 2, Eun Ji Song1, 2, Kyung Hoon Kim1, 2, Suk Soon Choi3, and Young-Seak Lee1, 2, †
  • 1Department of Chemical Engineering and Applied Chemistry, Chungnam National University, Daejeon 34134, Republic of Korea
  • 2Institute of Carbon Fusion Technology (InCFT), Chungnam National University, Daejeon 34134, Republic of Korea
  • 3Department of Biological and Environmental Engineering, Semyung University, Jecheon 27136, Republic of Korea
E-mail:
The textural (Brunauer-Emmett-Teller (BET)/density functional theory (DFT) surface energy) and chemical (oxygen-containing functional groups) properties of activated carbon fibers (ACFs) according to the electron-beam (E-beam) dose were investigated, and their dimethyl methylphosphonate (DMMP) gas sensing ability was tested. The E-beam attacked the basal plane in ACFs and generated additional lattice defects. The E-beam-irradiated ACFs exhibited a 22.2% change in resistance when upon exposure to DMMP gas. After E-beam irradiation, the surface energy of the ACFs increased because of increased roughness and oxygen-containing functional group content. As a result, the number of active sites capable of detecting DMMP increased, and the sensitivity increased.
Keywords:Adsorptive potential distribution;Nerve agent;Gas sensing;Electron beam;Dimethyl methylphosphonate (DMMP)
  1. Lee EC, JAMA, 290, 659 (2003)
  2. Sfrazzetto GT, Millesi S, Pappalardo A, Tomaselli GA, Ballistreri FP, Toscano RM, Fragala I, Gulino A, Chem. Eur. J., 23, 1576 (2017)
  3. Kong L, Wang J, Luo T, Meng F, Chen X, Li M, Liu J, Analyst, 135, 368 (2010)
  4. Climent E, Biyikal M, Gawlitza K, Dropa T, Urban M, Costero AM, Martinez-Manez R, Rurack K, Chem. Eur. J., 22, 11138 (2016)
  5. Kumar V, Rana H, Chem. Commun., 51, 16490 (2015)
  6. Wang L, Wang Z, Xiang Q, Chen Y, Duan Z, Xu J, Sens. Actuators B-Chem., 248, 820 (2017)
  7. Nasirian S, Moghaddam HM, Appl. Surf. Sci., 328, 395 (2015)
  8. Yang L, Yin C, Zhang Z, Zhou J, Xu H, Mater. Sci. Semicond. Process, 60, 16 (2017)
  9. Jang YJ, Kim K, Tsay OG, Atwood DA, Churchill DG, Chem. Rev., 115, PR1 (2015)
  10. Sung XL, Dahlhauser SD, Anslyn EV, J. Am. Chem. Soc., 139(13), 4635 (2017)
  11. Sun X, Anslyn EV, Angew. Chem.-Int. Edit., 56, 9522 (2017)
  12. Puglisi R, Pappalardo A, Gulino A, Sfrazzetto GT, Chem. Commun., 54, 11156 (2018)
  13. Bai BC, Bae TS, Carbon Lett., 18, 76 (2016)
  14. Kim MI, Lee YS, Appl. Chem. Eng., 25(2), 193 (2014)
  15. Xue L, Wang W, Guo Y, Liu G, Wan P, Sens. Actuators B-Chem., 244, 47 (2017)
  16. Chatterjee SG, Chatterjee S, Ray AK, Sens. Actuators B-Chem., 221, 1170 (2015)
  17. Jung MJ, Park MS, Lee YS, J. Nanomater., 16, 201 (2015)
  18. Park MS, Lee S, Jung MJ, Kim HG, Lee YS, Carbon Lett., 20, 19 (2016)
  19. Vijayaraghavan A, Kanzaki K, Suzuki S, Kobayashi Y, Inokawa H, Ono Y, Kar S, Ajayan PM, Nano Lett., 5, 1575 (2005)
  20. Park SJ, Kil HS, Choi DS, Song SK, Lee SH, J. Ind. Eng. Chem., 69, 449 (2019)
  21. Jo HJ, Jung MJ, Lee YS, Polym. Korea, 41(3), 500 (2017)
  22. Lavoie J, Srinivasan S, Nagarajan R, J. Hazard. Mater., 194, 85 (2011)
  23. Kim MJ, Lee S, Lee KM, Jo H, Choi SS, Lee YS, J. Ind. Eng. Chem., 341(2017).
  24. Lee SM, Jung MJ, Lee KM, Lee YS, Appl. Chem. Eng., 28(3), 299 (2017)
  25. Polak-Krasna K, Dawson R, Holyfield LT, Bowen CR, Burrows AD, Mays TJ, J. Mater. Sci., 52(7), 3862 (2017)
  26. Placke T, Siozios V, Schmitz R, Lux SF, Bieker P, Colle C, Meyer HW, Passerini S, Winter M, J. Power Sources, 200, 83 (2012)
  27. Foss CEL, Svensson AM, Sunde S, Vullum-Bruer F, J. Power Sources, 317, 177 (2016)
  28. Song EJ, Kim MJ, Han JI, Choi YJ, Lee YS, Appl. Chem. Eng., 30(2), 160 (2019)
  29. Smith M, Scudiero L, Espinal J, McEwen JS, Garcia-Perez M, Carbon, 110, 155 (2016)
  30. Gotovac S, Yang CM, Hattori Y, Takahashi K, Kanoh H, Kaneko K, J. Colloid Interface Sci., 314(1), 18 (2007)
  31. Gupta S, Patel RJ, Smith N, Giedd RE, Hui D, Diamond Relat. Mater., 16, 236 (2007)
  32. Im JS, Kang SC, Lee SH, Lee YS, Carbon, 48, 2573 (2010)
  33. Yoo R, Cho S, Song MJ, Lee W, Sens. Actuators B-Chem., 221, 217 (2015)
  34. Kim MJ, Kim KH, Yang X, Yu YH, Lee YS, J. Ind. Eng. Chem., 76, 181 (2019)
  35. Kang SC, Im JS, Lee SH, Bae TS, Lee YS, Colloids Surf. A: Physicochem. Eng. Asp., 384, 297 (2011)
  36. Lee JS, Kwon OS, Park SJ, Park EY, You SA, Yoon H, Jang J, ACS Nano, 5, 7992 (2011)
  37. Wang Y, Zhou Z, Yang Z, Chen X, Xu D, Zhang Y, Nanotechnology, 20, 345502 (2009)
  38. Park J, Kim J, Kim K, Kim SY, Cheong WH, Park K, Song JH, Namgoong GH, Kim JJ, Heo J, Bien F, Park JU, Nanoscale, 8, 10591 (2016)
  39. Galstyan V, Comini E, Baratto C, Faglia G, Sberveglieri G, Ceram. Int., 41, 14239 (2015)
  40. Tonezzer M, Lacerda RG, Sens. Actuators B-Chem., 150, 517 (2010)
  41. Lee SC, Choi HY, Lee SJ, Lee WS, Huh JS, Lee DD, Kim JC, Sens. Actuators B-Chem., 137, 239 (2009)
  42. Lee SC, Kim SY, Lee WS, Jung SY, Hwang BW, Ragupathy D, Lee DD, Lee SY, Kim JC, Sensors, 11, 6893 (2011)
  43. Kim HC, Hong SH, Kim SJ, Lee JH, J. Sens. Sci. Technol., 20, 294 (2011)
  44. Alali KT, Liu J, Aljebawi K, Liu Q, Chen R, Yu J, Zhang M, Wang J, J. Alloy. Compd., 780, 680 (2019)
  45. Alali KT, Liu J, Aljebawi K, Liu P, Chen R, Li R, Zhang H, Zhou L, Wang J, J. Alloy. Compd., 793, 31 (2019)
  46. Zhu Y, Cheng Z, Xiang Q, Chen X, Xu J, Sens. Actuators B-Chem., 248, 785 (2017)