아민기로 관능화된 마그네슘-층상규산염을 이용한 섬유유연제 제조

김성열; 최유성; Seong Yeol Kim; Yoo-Sung Choi

Applied Chemistry for Engineering, Vol.30, No.5, 580-585, October, 2019

DOI10.14478/ace.2019.1058 Export Citation

아민기로 관능화된 마그네슘-층상규산염을 이용한 섬유유연제 제조

Preparation of Fabric Softener Product by using Amine-functionalized Magnesium-phyllosilicates

김성열, 최유성^†

(주)럭키산업 연구개발팀

Seong Yeol Kim, and Yoo-Sung Choi^†

Lucky Research and Development Center (LRDC), Lucky Industry Co., Ltd., Gwangsan-gu, Gwangju 62230, Korea

E-mail:

초록

본 연구에서는 (3-aminopropyl)triethoxysilane을 사용하여 표면을 아민기로 관능화함과 동시에 팔면체와 사면체 구조를 가지는 마그네슘-층상규산염(AF-MgP)을 합성하였다. FT-IR과 XRD 분석을 통해 AF-MgP가 성공적으로 합성되었음과, 입자 표면의 아민기 및 1 : 2 비율의 팔면체와 사면체 구조를 확인하였다. HR-SEM와 EDX 분석을 통해 면섬유 표면에 AF-MgP가 고루 흡착되어 섬유를 코팅하고 있음을 확인하였다. KS 규격에 따른 섬유의 항균력 시험 결과 AF-MgP 입자가 코팅된 면섬유는 피부 상재균에 대해 매우 우수한 항균 활성을 나타내는 것을 확인하였다. 이상의 결과들은 AF-MgP가 섬유에 항균성을 부여해주는 기능성 나노 소재로서 적용될 뿐만 아니라, 화장품이나 의료 소재 분야에서 응용이 가능함을 시사한다.

In this study, we synthesized amine-functionalized magnesium-phyllosilicates (AF-MgP) with an octahedral and tetrahedral structure using (3-aminopropyl)triethoxysilane. The synthesis of AF-MgP, surface functionalization of amine and 1 : 2 ratio of the octahedral and tetrahedral structure were confirmed by FT-IR and XRD analysis. In addition, it was confirmed that AF-MgP was absorbed evenly on the surface of cotton fibers and coated on the cotton fibers from HR-SEM and EDX analysis. The antimicrobial activity test of cotton fibers according to KS confirmed that cotton fibers coated with AF-MgP particles show an enhanced antimicrobial activity against cutaneous microorganisms. Our results suggest that AF-MgP is not only applied as a functional nanomaterial that gives the cotton fiber antimicrobiality, but also can be used in the field of cosmetic and biomedical materials.

Keywords:Mg-phyllosilicate;Amine-functionalization;One-pot synthesis;Antimicrobial;Fabric softener

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Chandrasekaran G, Han HK, Kim GJ, Shin HJ, Appl. Clay Sci., 53, 729 (2011)
Kim SY, Choi YS, Appl. Chem. Eng., 30(2), 254 (2019)
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[1] Dastjerdi R, Montazer M, Colloids Surf. B: Biointerfaces, 79, 5 (2010)

[2] Grice EA, Segre JA, Nat. Rev. Microbiol., 9, 244 (2011)

[3] Lin J, Chen X, Chen C, Hu J, Zhou C, Cai X, Wang W, Zheng C, Zhang P, Cheng J, Guo Z, Liu H, ACS Appl. Mater. Interfaces, 10, 6124 (2018)

[4] Mao T, Wei Y, Zheng C, Cheng W, Zhang Z, Zhu Y, Wang R, Zeng Z, J. Surfactants Deterg., DOI:10.1002/jsde.12316 (2019).

[5] Lee YH, Lee SG, Hwang EK, Baek YM, Cho S, Kim JS, Kim HD, J. Text. Sci. Eng., 53, 45 (2016)

[6] Wu M, Ma B, Pan T, Chen S, Sun J, Adv. Func. Mater., 26, 569 (2016)

[7] Shaheen TI, El-Naggar ME, Abdelgawad AM, Hebeish A, Int. J. Biol. Macromol., 83, 426 (2016)

[8] El-Naggar ME, Shaheen TI, Zaghloul S, El-Rafie MH, Hebeish A, Ind. Eng. Chem. Res., 55(10), 2661 (2016)

[9] Rosalind JHA, Anderson C, J. Toxicol. Environ. Health, 60, 121 (2000)

[10] Oikonomou EK, Christov N, Cristobal G, Bourgaux C, Heux L, Boucenna I, Berret JF, J. Colloid Interface Sci., 525, 206 (2018)

[11] Calero N, Santos J, Barjano M, Munos J, J. Surfactants Deterg., 19, 609 (2016)

[12] Ravichandran V, Vasanthi S, Shalini S, Shah SAA, Harish R, Mater. Lett., 180, 264 (2016)

[13] Bonilla J, Sobral PJA, Food Biosci., 16, 17 (2016)

[14] Mpala L, Chikowe G, Cock IE, Pharmacogn. Commun, 9, 75 (2019)

[15] Velmurugan P, Kim JI, Kim K, Park JH, Lee KJ, Chang WS, Park YJ, Cho M, Oh BT, J. Photochem. Photobiol., 173, 571 (2017)

[16] Ghoreishian SM, Maleknia L, Mirzapour H, Norouzi M, Fiber. Polym., 14, 201 (2013)

[17] Ke GZ, Yu WD, Xu WL, J. Appl. Polym. Sci., 101(5), 3376 (2006)

[18] Lee Y, Choi Y, Choi M, Yang H, Liu K, Shin H, Appl. Clay Sci., 83, 474 (2013)

[19] Kim SY, Choi YS, Colloids Surf. A: Physicochem. Eng. Asp., 569, 164 (2019)

[20] Bian Z, Kawi S, Catal. Today, DOI:10.1016/j.cattod.2018.12.030.

[21] Datta KKR, Achari A, Eswaramoorthy M, J. Mater. Chem. A, 1, 6707 (2013)

[22] Han HK, Lee YC, Lee MY, Patil AJ, Shin HJ, ACS Appl. Mater., 3, 2564 (2011)

[23] Chandrasekaran G, Han HK, Kim GJ, Shin HJ, Appl. Clay Sci., 53, 729 (2011)

[24] Kim SY, Choi YS, Appl. Chem. Eng., 30(2), 254 (2019)

[25] Kim SY, Choi YS, Appl. Chem. Eng., 28(5), 495 (2017)

[26] Gordon S, Hsieh YL, Cotton: Science and Technology, 3-5, UK (2006).

[27] Kulthong K, Srisung S, Boonpavanitchakul K, Kangwansupamonkon W, Maniratanachote R, Part. Fibre Toxicol., 7(8) (2010)