화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.80, 112-121, December, 2019
DOI10.1016/j.jiec.2019.07.038  Export Citation
Synthesis of poly[2-(3-butenyl)-2-oxazoline] with abundant carboxylic acid functional groups as a fiber-based sol-gel reaction supporter for catalytic applications
Wu Bin Ying1, 2, Kihyeon Bae2, Na Yeong Ko2, Soo Hee Kim3, Sam Gon Ryu4, Jin Zhu1, Ruoyu Zhang1, †, Bumjae Lee2, †, and Kyung Jin Lee2, †
  • 1Key Laboratory of Bio-Based Polymeric Materials Technology and Application of Zhejiang Province, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, No. 1219, West Zhongguan Road, Zhenhai District, Ningbo, Zhejiang 315201, People’s Republic of China
  • 2Department of Fine Chemical Engineering and Applied Chemistry, Chungnam National University, 220 Gung-dong, Yuseong-gu, Daejeon 305-764, South Korea
  • 3Center for Membranes, Korea Research Institute of Chemical Technology, 141 Gajeong-ro, Yuseong-gu, Daejeon 34114, South Korea
  • 4The 5th Research and Development Institute, Agency for Defense Development, Yuseong-Gu, Daejeon 305-600, South Korea
E-mail:, ,
Polymer-based catalysts have been of special interest because of their several advantages such as easy processibility. Inorganic catalyst generally have been introduced into polymer-based media to endow catalytic activity. Surface decoration or sol-gel reaction have been performed so far, but inherent low affinity between organic/inorganic causes low efficiency in loading amount, resulting in low catalytic activity. Herein, we synthesized easily processible and highly functionalizable polyoxazoline as polymer nonwoven fiber-based catalytic supporter. Zr(OH)4 was grown on surface of fiber-web via sol-gel reaction. The Zr(OH)4 grown fiber exhibited not only excellent mechanical properties but also effective decontamination efficiency against organophosphate-based toxic agents.
Keywords:Organophosphate-based toxic agents;Polyamide;Pesticides;Zirconium hydroxide
  1. Reichelt E, Heddrich MP, Jahn M, Michaelis A, Appl. Catal. A: Gen., 476, 78 (2014)
  2. Xu P, Wei B, Cao Z, Zheng J, Gong K, Li F, Yu J, Li Q, Lu W, Byun JH, Kim BS, Yan Y, Chou TW, ACS Nano, 9, 6088 (2015)
  3. Liu XL, Demir NK, Wu ZT, Li K, J. Am. Chem. Soc., 137(22), 6999 (2015)
  4. Li XS, Chou SR, Wang R, Shi L, Fang WX, Chaitra G, Tang CYY, Torres J, Hu X, Fane AG, J. Membr. Sci., 494, 68 (2015)
  5. Souzandeh H, Johnson KS, Wang Y, Bhamidipaty K, Zhong WH, ACS Appl. Mater. Interfaces, 8, 20023 (2016)
  6. Tian C, Zhu L, Lin F, Boyes SG, ACS Appl. Mater. Interfaces, 7, 17765 (2015)
  7. Cao HL, Huang HB, Chen Z, Karadeniz B, Lu J, Cao R, ACS Appl. Mater. Interfaces, 9, 5231 (2017)
  8. Duan J, Jin W, Kitagawa S, Coord. Chem. Rev., 332, 48 (2017)
  9. Bai Y, Dou Y, Xie LH, Rutledge W, Li JR, Zhou HC, Chem. Soc. Rev., 45, 2327 (2016)
  10. Howarth AJ, Liu Y, Li P, Li Z, Wang TC, Hupp JT, Farha OK, Nat. Rev. Mater., 1, 15018 (2016)
  11. Rimoldi M, Howarth AJ, DeStefano MR, Lin L, Goswami S, Li P, Hupp JT, Farha OK, ACS Catal., 7, 997 (2016)
  12. Gupta KM, Zhang K, Jiang JW, Langmuir, 31(48), 13230 (2015)
  13. Galizia M, Chi WS, Smith ZP, Merkel TC, Baker RW, Freeman BD, Macromolecules, 50(20), 7809 (2017)
  14. Xu Y, Wang TQ, He ZD, Zhou MH, Yu W, Shi BY, Huang K, Macromolecules, 50(24), 9626 (2017)
  15. Friebe S, Mundstock A, Volgmann K, Caro J, ACS Appl. Mater. Interfaces, 9, 41553 (2017)
  16. Zhu J, Qin L, Uliana A, Hou J, Wang J, Zhang Y, Li X, Yuan S, Li J, Tian M, Lin J, Bruggen BV, ACS Appl. Mater. Interfaces, 9, 1975 (2017)
  17. Regonini D, Teloeken AC, Alves AK, Berutti FA, Gajda-Schrantz K, Bergmann CP, Graule T, Clemens F, ACS Appl. Mater. Interfaces, 5, 11747 (2013)
  18. Raza A, Ding B, Zainab G, El-Newehy M, Al-Deyab SS, Yu J, J. Mater. Chem. A, 2, 10137 (2014)
  19. Peng X, Santulli AC, Sutter E, Wong SS, Chem. Sci., 3, 1262 (2012)
  20. Chen M, Wang C, Fang W, Wang J, Zhang W, Jin G, Diao G, Langmuir, 29, 11858 (2013)
  21. Qin D, Yu J, Bian G, Qi Y, Zhang D, Yang X, Chin. J. Chem., 32, 163 (2014)
  22. Kim S, Ying WB, Jung H, Ryu SG, Lee B, Lee KJ, Chem. Asian J., 12, 698 (2017)
  23. Bachman JE, Smith ZP, Li T, Xu T, Long JR, Nat. Mater., 15(8), 845 (2016)
  24. Feinle A, Elsaesser MS, Huesing N, Chem. Soc. Rev., 45, 3377 (2016)
  25. Salunkhe RR, Tang J, Kamachi Y, Nakato T, Kim JH, Yamauchi Y, ACS Nano, 9, 6288 (2015)
  26. Arslan O, Aytac Z, Uyar T, ACS Appl. Mater. Interfaces, 8, 19747 (2016)
  27. Arslan O, Uyar T, Nanoscale, 9, 9606 (2017)
  28. Fu Y, Sun D, Chen Y, Huang R, Ding Z, Fu X, Li Z, Angew. Chem.-Int. Edit., 124, 3420 (2012)
  29. Wang Y, Zhao Q, Zhang H, Yang S, Jia XR, Adv. Mater., 26(24), 4163 (2014)
  30. Xu YL, Xu HJ, Jiang XS, Yin J, Adv. Funct. Mater., 24(12), 1679 (2014)
  31. Seo BB, Koh JT, Song SC, Biomaterials, 122, 91 (2017)
  32. van Hoorick J, Gruber P, Markovic M, Tromayer M, Van Erps J, Thienpont H, Liska R, Ovsianikov A, Dubruel P, Van Vlierberghe S, Biomacromolecules, 18(10), 3260 (2017)
  33. Verdolotti L, Lavorgna M, Lamanna R, Di Maio E, Iannace S, Polymer, 56, 20 (2015)
  34. Figueira RB, Silva CJ, Pereira EV, J. Coat. Technol. Res., 12, 1 (2015)
  35. Fu C, Hu X, Yang Z, Shen L, Zheng Z, Prog. Org. Coat., 84, 18 (2015)
  36. Gress A, Volkel A, Schlaad H, Macromolecules, 40(22), 7928 (2007)
  37. Ying WB, Kim S, Lee MW, Go NY, Jung H, Ryu SG, Lee B, Lee KJ, RSC Adv., 7, 15246 (2017)
  38. Castagna R, Momente R, Pariani G, Zerbi G, Bianco A, Bertarelli C, Polym. Chem., 5, 6779 (2014)
  39. Winnacker M, Rieger B, Polym. Chem., 7, 7039 (2016)
  40. Li P, Hu B, Li X, J. Chromatogr. A, 1247, 49 (2012)
  41. Dargaville TR, Lava K, Verbraeken B, Hoogenboom R, Macromolecules, 49(13), 4774 (2016)
  42. Legros C, De Pauw-Gillet MC, Tam KC, Taton D, Lecommandoux S, Soft Matter, 11, 3354 (2015)
  43. Mansfeld U, Hoeppener S, Kempe K, Schumers JM, Gohy JF, Schubert US, Soft Matter, 9, 5966 (2013)
  44. Rossegger E, Schenk V, Wiesbrock F, Polymers, 5, 956 (2013)
  45. Chan JM, Ke X, Sardon H, Engler AC, Yang YY, Hedrick JL, Chem. Sci., 5, 3294 (2014)
  46. Silverstein RM, Webster FX, Kiemle DJ, Spectrometric Identification of Organic Compounds, 7th edition, John Wiley& Sons, Hoboken, pp.153 2005.
  47. Kostova B, Ivanova-Mileva K, Rachev D, Christova D, AAPS PharmSciTech, 14, 352 (2013)
  48. Tsunetsugu T, Furukawa J, Fueno T, J. Polym. Sci. Polym. Chem., 9, 3529 (1971)
  49. Qin DB, Yan EW, Yu JH, Zhang W, Liu B, Yang XL, Mater. Chem. Phys., 136(2-3), 688 (2012)
  50. Bobbitt NS, Mendonca ML, Howarth AJ, Islamoglu T, Hupp JT, Farha OK, Snurr RQ, Chem. Soc. Rev., 46, 3357 (2017)
  51. Moon SY, Liu Y, Hupp JT, Farha OK, Angew. Chem.-Int. Edit., 54, 6795 (2015)
  52. Stengl V, Houskova V, Bakardjieva S, Murafa N, Marikova M, Oolusitl F, Nemec T, Mater. Charact., 61, 1080 (2010)
  53. Mondloch JE, Katz MJ, Isley WC, Ghosh P, Liao PL, Bury W, Wagner G, Hall MG, DeCoste JB, Peterson GW, Snurr RQ, Cramer CJ, Hupp JT, Farha OK, Nat. Mater., 14(5), 512 (2015)
  54. Tenhaeff WE, Gleason KK, Adv. Funct. Mater., 18(7), 979 (2008)
  55. Lopez-Maya E, Montoro C, Rodriguez-Albelo LM, Cervantes SDA, Lozano-Perez AA, Cenis JL, Barea E, Navarro JA, Angew. Chem.-Int. Edit., 54, 6790 (2015)
  56. Gil-San-Millan R, Lo’pez-Maya E, Hall M, Padial NM, Peterson GW, DeCoste JB, Rodriguez-Albelo LM, Oltra JE, Barea E, Navarro JA, ACS Appl. Mater. Interfaces, 9, 23967 (2017)
  57. de Koning MC, van Grol M, Breijaert T, Inorg. Chem., 56(19), 11804 (2017)
  58. Liu Y, Moon SY, Hupp JT, Farha OK, ACS Nano, 9, 12358 (2015)
  59. Zhao J, Lee DT, Yaga RW, Hall MG, Barton HF, Woodward IR, Oldham CJ, Walls HJ, Peterson GW, Parsons GN, Angew. Chem.-Int. Edit., 55, 13224 (2016)
  60. Bacalum E, Cheregi M, David V, Rev. Roum. Chim., 57, 427 (2012)
  61. Segall Y, Waysbort D, Barak D, Ariel N, Doctor BP, Grunwald J, Ashani Y, Biochemistry, 32, 13441 (1993)