화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.27, No.11, 1089-1094, November, 2019
DOI10.1007/s13233-019-7151-z  Export Citation
Magnetic Molecularly Imprinted Polymer Particles Based Micro-Solid Phase Extraction for the Determination of 4-Nitrophenol in Lake Water
Aziguli Yigaimu1, Turghun Muhammad1, 2, †, Wenwu Yang1, Imran Muhammad1, Muyasier Wubulikasimu1, and Sergey A. Piletsky3
  • 1College of Chemistry & Chemical Engineering, Xinjiang Key laboratory of Oil and Gas Fine Chemicals, Xinjiang University, Urumqi 830046, P. R. China
  • 2State Key Laboratory of Fine Chemicals,, Dalian University of Technology, 2 Linggong Road, Dalian, P. R. China
  • 3University of Leicester, Department of Chemistry, LE1 7RH, UK
E-mail:
In this work, magnetic molecularly imprinted polymers (MMIPs) were prepared by the method of co-precipitation polymerization on the surface of vinyl-modified silica magnetic particles. Here, 4-nitrophenol (4-NP) was used as a template and vinylimidazole as a functional monomer. The structural features and morphology of MMIPs were characterized by SEM, FT-IR, TEM and XRD techniques. The results showed that the structures of MMIPs have a layer of silica and MIPs on the surface of the Fe3O4 particles, and they could be rapidly separated from the solution using a magnet. MMIPs possess higher adsorption capacity and excellent selectivity towards template (4-NP) than other structural analogues. And it is found to have good imprinting effect. MMIPs were used as micro-solid phase extraction sorbent for selective separation of 4-NP in lake water sample with high recoveries (90.63?95.63%) and low relative standard deviation values (RSD ≤ 3.2%, n = 3).
Keywords:molecularly imprinted polymers;magnetic separation;micro-solid phase extraction;4-nitrophenol
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