화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.36, No.12, 2008-2022, December, 2019
DOI10.1007/s11814-019-0384-x  Export Citation
Evaluation of novel Mg/Al/Ni-BaFe ternary layered hydroxides uptake of methyl orange dye from water
Nuhu Dalhat Mu’azu1, †, Nabeel Jarrah2, Mukarram Zubair1, Mohammad Saood Manz1, Taye Saheed Kazeem3, and Mamdouh Al-Harthi4, 5
  • 1Department of Environmental Engineering, Imam Abdulrahman Bin Faisal University, Dammam 31451, Saudi Arabia
  • 2Department of Chemical Engineering, Mutah University, Karak 61710, Jordan
  • 3Department of Civil Environmental Engineering, King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi Arabia
  • 4Department of Chemical Engineering, King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi Arabia
  • 5Center of Research Excellences in Nanotechnology, King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi Arabia
E-mail:
MgAlNi-BaFe ternary layered hydroxide (UMLDH) and its calcined (CMLDH) form were synthesized and tested as adsorbents for methyl orange dye (MO) uptake from water. The adsorptive performances of the new magnetic nanocomposites were modeled, evaluated and optimized via response surface methodology (RSM). The UMLDH and CMLDH maximum removal efficiency and adsorption capacities data were fitted into RSM models with insignificant lack of fit (p-values<0.05) and high R2=0.991-0.997. The UMLDH and CMLDH MO adsorption capacities increased with decrease in both pH and initial MO concentration and decreased when the temperature was increased. Under optimal operating conditions, pseudo-second-order described kinetics of MO sorption on the nanocomposites, while the Freundlich isotherm gave the best fits for both the two adsorbents. The MO uptake simultaneously incorporated both mono and multi-layer surface adsorption involving strong electrostatic attraction and chemical interactions between MO and the adsorbents surface functional groups. Respectively, the obtained maximum Langmuir theoretical sorption capacity of 715.44 and 708mg/g, indicated profoundly improved MO sorption capacities compared with many other magnetic-LDHs. These results demonstrate the potential of MgAlNi-BaFe as excellent adsorbents for effective remediation of dyes wastewater effluents.
Keywords:Barium Ferrite LDH;MgAlNi Nanocomposites;Methyl Orange Dye Uptake;Response Surface Methodology
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