화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.81, 206-218, January, 2020
DOI10.1016/j.jiec.2019.09.010  Export Citation
Preparation of Pd/SAPO-34/PSS composite membranes for hydrogen separation: Effect of crystallization time on the zeolite growth on PSS support
Afshin Dehghani Kiadehi, Majid Taghizadeh†, and Mohammad Darzinezhad Rami
  • Chemical Engineering Department, Babol Noshirvani University of Technology, P.O. Box 484, Babol 4714871167, Iran
E-mail:
In this study, palladium composite membranes were fabricated on porous stainless steel (PSS) supports using silicoaluminophosphate (SAPO) zeolite (SAPO-34) as a diffusion barrier and substrate modifier. The vacuum-assisted seeding and secondary growth method was used to coat the SAPO-34 zeolite layer on the PSS substrates. The morphologies and microstructures of the membranes were analyzed by AFM, XRD, BET, ICP.AES, FESEM and EDX techniques. The effect of crystallization time (24, 48 and 72 h) on the morphology and quality of SAPO-34 modified supports was studied. A continuous palladium layer with a thickness of about 9 mm was deposited on the SAPO-34 modified PSS support (72 h crystallization time) by electroless plating (ELP) route. The hydrogen permeation tests were carried out in the feed pressures range of 2-4 bar and various temperatures (623, 673 and 723 K). The values of the hydrogen permeance and ideal selectivity of H2/N2 for the PSM3 membrane were achieved 7.1 x 10-7 mol m-2 s-1 Pa-1 and 866, respectively a feed pressure of 2 bar and 723 K. In addition, the PSM3 membrane showed perfect stability during 260 h hydrogen permeation experiment at a feed pressure of 2 bar and 623 K.
Keywords:Palladium membrane;Hydrogen purification;Porous stainless steel;SAPO-34 zeolite;Seeding and secondary growth
  1. Kiadehi AD, Taghizadeh M, Int. J. Hydrog. Energy, 43(10), 4826 (2018)
  2. Tajrishi OZ, Taghizadeh M, Kiadehi AD, Int. J. Hydrog. Energy, 43(31), 14103 (2018)
  3. Lee C, Na H, Jeon Y, Hwang HJ, Kim HJ, Mochida I, Yoon SH, Park JI, Shul YG, J. Ind. Eng. Chem. (2019).
  4. Yoon KS, Lee JY, Kim TH, Yu DM, Seo DW, Hong SK, Hong YT, J. Ind. Eng. Chem., 20(4), 2310 (2014)
  5. Ehteshami SMM, Taheri A, Chan SH, J. Ind. Eng. Chem., 34, 1 (2016)
  6. Vijayakumar V, Nam SY, J. Ind. Eng. Chem. (2018).
  7. Kim DJ, Jo MJ, Nam SY, J. Ind. Eng. Chem., 21, 36 (2015)
  8. Xomeritakis G, Lin YS, J. Membr. Sci., 120(2), 261 (1996)
  9. Li AW, Liang WQ, Hughes R, Sep. Purif. Technol., 15(2), 113 (1999)
  10. Chen WD, Hu XJ, Wang RX, Huang Y, Sep. Purif. Technol., 72(1), 92 (2010)
  11. Xomeritakis G, Lin YS, AIChE J., 44(1), 174 (1998)
  12. Chen HI, Shiau JD, Chu CY, Huang TC, Sep. Purif. Technol., 32(1-3), 247 (2003)
  13. Yang J, Fan WQ, Bell CM, Sep. Purif. Technol., 210, 659 (2019)
  14. Yu J, Zhang J, Bao C, Li H, Xu H, Sun J, Sep. Purif. Technol., 184, 43 (53)
  15. Wang WP, Pan XL, Zhang XL, Yang WS, Xiong GX, Sep. Purif. Technol., 54(2), 262 (2007)
  16. Orakwe I, Shehu H, Gobina E, Int. J. Hydrog. Energy, 44(20), 9914 (2019)
  17. Calles JA, Sanz R, Alique D, Furones L, Marin P, Ordonez S, Sep. Purif. Technol., 194, 10 (2018)
  18. Kiadehi AD, Taghizadeh M, Int. J. Hydrog. Energy, 44(5), 2889 (2019)
  19. Lin YM, Rei MH, Sep. Purif. Technol., 25(1-3), 87 (2001)
  20. Xie DL, Wang F, Wu K, Zhang ET, Zhang YJ, Sep. Purif. Technol., 89, 189 (2012)
  21. Tosto E, Alique D, Martinez-Diaz D, Sanz R, Calles JA, Caravella A, Medrano JA, Gallucci F, Int. J. Hydrogen Energy (2019).
  22. Uemiya S, Sato N, Ando H, Kude Y, Matsuda T, Kikuchi E, J. Membr. Sci., 56, 303 (1991)
  23. Bhandari R, Ma YH, J. Membr. Sci., 334(1-2), 50 (2009)
  24. Nordio M, Soresi S, Manzolini G, Melendez J, Annaland MV, Tanaka DAP, Gallucci F, Int. J. Hydrog. Energy, 44(8), 4228 (2019)
  25. de Nooijer N, Plazaola AA, Rey JM, Fernandez E, Tanaka DAP, van Sint Annaland M, Gallucci F, Processes, 7, 106 (2019)
  26. Gallucci F, Basile A, Tosti S, Lulianelli A, Drioli E, Int. J. Hydrog. Energy, 32(9), 1201 (2007)
  27. Gallucci F, Medrano J, Fernandez E, Melendez J, van Sint Annaland M, Pacheco-Tanaka D, J. Membr. Sci. Res., 3, 142 (2017)
  28. Melendez J, Fernandez E, Gallucci F, Annaland MV, Arias PL, Tanaka DAP, J. Membr. Sci., 528, 12 (2017)
  29. Liu J, Bellini S, de Nooijer NC, Sun Y, Tanaka DAP, Tang C, Li H, Gallucci F, Caravella A, Int. J. Hydrogen Energy (2019).
  30. Huang Y, Liu Q, Jin X, Ding W, Hu X, Li H, Int. J. Hydrogen Energy (2019).
  31. Yun S, Oyama ST, J. Membr. Sci., 375(1-2), 28 (2011)
  32. Li A, Grace JR, Lim CJ, J. Membr. Sci., 298(1-2), 175 (2007)
  33. Jemaa N, Shu J, Kaliaguine S, Grandjean BP, Ind. Eng. Chem. Res., 35(3), 973 (1996)
  34. Samingprai S, Tantayanon S, Ma YH, J. Membr. Sci., 347(1-2), 8 (2010)
  35. Nam SE, Lee KH, J. Membr. Sci., 170(1), 91 (2000)
  36. Nam SE, Lee KH, J. Membr. Sci., 192(1-2), 177 (2001)
  37. Su CL, Jin T, Kuraoka K, Matsumura Y, Yazawa T, Ind. Eng. Chem. Res., 44(9), 3053 (2005)
  38. Gao HY, Lin JYS, Li YD, Zhang BQ, J. Membr. Sci., 265(1-2), 142 (2005)
  39. Zahedi M, Afra B, Dehghani-Mobarake M, Bahmani M, J. Membr. Sci., 333(1-2), 45 (2009)
  40. Huang Y, Dittmeyer R, J. Membr. Sci., 282(1-2), 296 (2006)
  41. Yepes D, Cornaglia LM, Irusta S, Lombardo EA, J. Membr. Sci., 274(1-2), 92 (2006)
  42. Lee SM, Xu N, Kim SS, Li AW, Grace JR, Lim CJ, Boyd T, Ryi SK, Susdorf A, Schaadt A, J. Membr. Sci., 541, 1 (2017)
  43. Medrano JA, Fernandez E, Melendez J, Parco M, Tanaka DAP, Annaland MV, Gallucci F, Int. J. Hydrog. Energy, 41(20), 8706 (2016)
  44. Chen WH, Lin SW, Chen CY, Chi YH, Lin YL, Int. J. Hydrogen Energy (2019).
  45. Martinez-Diaz D, Sanz R, Calles JA, Alique D, Sep. Purif. Technol., 216, 16 (2019)
  46. Sun Q, Wang N, Bing Q, Si R, Liu J, Bai R, Zhang P, Jia M, Yu J, Chem, 3, 477 (2017)
  47. Bosko ML, Ojeda F, Lombardo EA, Cornaglia LM, J. Membr. Sci., 331(1-2), 57 (2009)
  48. Wang X, Tan X, Meng B, Zhang X, Liang Q, Pan H, Liu S, RSC Adv., 3, 4821 (2013)
  49. Mobarake MD, Jafari P, Irani M, Microporous Mesoporous Mater., 226, 369 (2016)
  50. Guo Y, Zhang XF, Deng H, Wang XB, Wang Y, Qiu JS, Wang JQ, Yeung KL, J. Membr. Sci., 362(1-2), 241 (2010)
  51. Hong M, Li SG, Falconer JL, Noble RD, J. Membr. Sci., 307(2), 277 (2008)
  52. Das JK, Das N, Bandyopadhyay S, J. Mater. Chem. A, 1, 4966 (2013)
  53. Sun Q, Wang N, Bai R, Hui Y, Zhang T, Do DA, Zhang P, Song L, Miao S, Yu J, Adv. Sci., 1802350 (2019).
  54. Wang N, Sun Q, Yu J, Adv. Mater., 31, 180396 (2019)
  55. Fatourehchi N, Sohrabi M, Royaee SJ, Mirarefin SM, Chem. Eng. Res. Des., 89(6A), 811 (2011)
  56. Zhong J, Han J, Wei Y, Xu S, He Y, Zheng Y, Ye M, Guo X, Song C, Liu Z, Chem. Commun., 54, 3146 (2018)
  57. Rami MD, Taghizadeh M, Akhoundzadeh H, Microporous Mesoporous Mater., 285, 259 (2019)
  58. Fischer M, Phys. Chem. Chem. Phys., 17, 25260 (2015)
  59. Sun Q, Xie Z, Yu J, Natl. Sci. Rev., 5, 542 (2017)
  60. Guangyu L, Peng T, Zhongmin L, Chin. J. Catal., 33, 174 (2012)
  61. Aghaei E, Haghighi M, Powder Technol., 269, 358 (2015)
  62. Akhoundzadeh H, Taghizadeh M, Pajaie HS, Particuology (2018).
  63. Shi ZL, Wu SQ, Szpunar JA, Roshd M, J. Membr. Sci., 280(1-2), 705 (2006)
  64. Guo Y, Jin YJ, Wu HM, Zhou LD, Chen QQ, Zhang XF, Li XX, Int. J. Hydrog. Energy, 39(36), 21044 (2014)
  65. Guazzone F, Ma YH, AIChE J., 54(2), 487 (2008)
  66. Zhang XL, Xiong GX, Yang WS, J. Membr. Sci., 314(1-2), 226 (2008)
  67. Sato K, Natsui M, Hasegawa Y, Mater. Trans., MF201402 (2015).
  68. Fernandez E, Medrano JA, Melendez J, Parco M, Viviente JL, Annaland MV, Gallucci F, Tanaka DAP, Chem. Eng. J., 305, 182 (2016)
  69. Fernandez E, Helmi A, Coenen K, Melendez J, Viviente JL, Tanaka DAP, Annaland MV, Gallucci F, Int. J. Hydrog. Energy, 40(8), 3506 (2015)
  70. Chi YH, Lin JJ, Lin YL, Yang CC, Huang JH, J. Membr. Sci., 475, 259 (2015)
  71. Fontana AD, Sirini N, Cornaglia LM, Tarditi AM, J. Membr. Sci., 563, 351 (2018)
  72. Contardi I, Cornaglia L, Tarditi AM, Int. J. Hydrog. Energy, 42(12), 7986 (2017)
  73. Guo Y, Wu HM, Jin YJ, Zhou LD, Chen QQ, Fan XF, Int. J. Hydrog. Energy, 42(44), 27111 (2017)
  74. Liguori S, Iulianelli A, Dalena F, Pinacci P, Drago F, Broglia M, Huang Y, Basile A, Membranes, 4, 143 (2014)
  75. Kian K, Woodall C, Wilcox J, Liguori S, Environments, 5, 128 (2018)
  76. Furones L, Alique D, ChemEngineering, 2, 1 (2018)
  77. Ward TL, Dao T, J. Membr. Sci., 153(2), 211 (1999)
  78. Alique D, Martinez-Diaz D, Sanz R, Calles J, Membranes, 8, 5 (2018)
  79. Watanabe Y, Koiwai A, Takeuchi H, Hyodo SA, Noda S, J. Catal., 143, 430 (1993)
  80. Liu G, Tian P, Li J, Zhang D, Zhou F, Liu Z, Microporous Mesoporous Mater., 111, 143 (2008)
  81. Tong J, Su L, Haraya K, Suda H, Chem. Commun., 1142 (2006).