Synthesis of sulfonated polyketone membranes by a direct sulfonation reaction and their properties

Seong Yeon Hwang; Jae Bum An; Byoung Chul Park; Taekeun Kim; Taek Sung Hwang

Journal of Industrial and Engineering Chemistry, Vol.81, 464-474, January, 2020

DOI10.1016/j.jiec.2019.09.036 Export Citation

Synthesis of sulfonated polyketone membranes by a direct sulfonation reaction and their properties

Seong Yeon Hwang, Jae Bum An, Byoung Chul Park, Taekeun Kim, and Taek Sung Hwang^†

Department of Chemical Engineering, College of Engineering, Chungnam National University, 99 Daehak-ro, Yuseoung-gu, Daejeon 34134, Republic of Korea

E-mail:

In this study, sulfonated polyketone cation exchange (SPOK) membranes were prepared by a direct sulfonation method and evaluated according to the concentration of sulfonating agent, reaction time and reaction temperature. The physicochemical properties of these membranes were measured to confirm their optimal synthetic conditions. The sulfur content in the SPOK membranes increased with increasing sulfonating agent concentration, reaction time and reaction temperature. The ion exchange capacity, water uptake and swelling ratio of these membranes increased with increasing sulfur content. The highest ion exchange capacity for the membranes was 1.01 meq/g. From the measured electrical properties, the electrical resistance showed a tendency to decrease with increasing sulfonation conversion, and the lowest electrical resistance was 0.4 Ω cm2 when the sulfonation conversion was 59.6%. To evaluate the possible application of the SPOK membranes to membrane capacitive deionization (MCDI) modules, their chemical resistance, durability and tensile strength were measured. The performance-limiting conditions for the tensile strength were 0.3 wt% chlorosulfonic acid (CSA)/CF, 20 °C and 60 min.

Keywords:Polyketone;Sulfonated cation exchange membrane

[References]

Warsinger DM, Prog. Polym. Sci., 81, 209 (2018)
Goh PS, Matsuura T, Ismail AF, Hilal N, Desalination, 391, 43 (2016)
Brant J, Kwan P, State-of-the-Science Review of Membrane Fouling: Organic, Inorganic, and Biological. Tech. Rep.06-10 (Phase A), California Department of water resources, 2013.
Huang H, Schwab K, Jacangelo JG, Environ. Sci. Technol., 43(9), 3011 (2009)
National Research Council, Water Reuse, National Academies Press, 2012.
Cipollina A, Micale G, Rizzuti L(Eds.), Seawater Desalination: Conventional and Renewable Energy Processes, Springer Science & Business Media, 2009.
Anderson MA, Cudero AL, Palma J, Electrochim. Acta, 55(12), 3845 (2010)
Arnold BB, Murphy GW, J. Phys. Chem., 65(1), 135 (1961)
Biesheuvel PM, Zhao R, Porada S, van der Wal A, J. Colloid Interface Sci., 360(1), 239 (2011)
Luo T, Abdu S, Wessling M, J. Membr. Sci., 555, 429 (2018)
Drent E, et al., Encyclopedia of Polymer Science and Technology, Polyketones, vol. 3, John Wiley, 2011.
Jung YS, Canlier A, Hwang TS, Polymer, 141, 102 (2018)
Hyosung Polyketone, http://www.poly-ketone.co.kr.
Guo JT, Ye YQ, Gao S, Feng YK, J. Mol. Catal. A-Chem., 307(1-2), 121 (2009)
Mul WP, Dirkzwager H, Broekhuis AA, Heeres HJ, van der Linden AJ, Orpen AG, Inorg. Chim. Acta., 327(1), 147 (2002)
Bianchini C, Meli A, Coord. Chem. Rev., 225(1-2), 35 (2002)
Rivas BL, Pereira ED, Moreno-Villoslada I, Prog. Polym. Sci., 28(2), 173 (2003)
Zagorodni AA, Ion Exchange Materials: Properties and Applications, Elsevier, 2006.
Ataollahi N, Vezzu K, Nawn G, Pace G, Cavinato G, Girardi F, Scardi P, Di Noto V, Di Maggio R, Electrochim. Acta, 226, 148 (2017)
Ohsawa O, Lee KH, Kim BS, Lee S, Kim IS, Polymer, 51(9), 2007 (2010)
Nam JU, Choi EY, Park HJ, Kim CK, Compos. Sci. Technol., 167, 199 (2018)
Kim IS, Hwang CW, Kim YJ, Canlier A, Jeong KS, Hwang TS, Macromol. Res., 25(11), 1063 (2017)
Banerjee S, Kar KK, Polymer, 109, 176 (2017)
Mauritz KA, Moore RB, Chem. Rev., 104(10), 4535 (2004)
Jin X, Bishop MT, Ellis TS, Karasz FE, Br. Polym. J., 17(1), 4 (1985)
Wang F, Hickner M, Kim YS, Zawodzinski TA, McGrath JE, J. Membr. Sci., 197(1-2), 231 (2002)
Knauth P, Hou H, Bloch E, Sgreccia E, Di Vona ML, J. Anal. Appl. Pyrolysis, 92(2), 361 (2011)
Kumar M, Tripathi BP, Shahi VK, Ind. Eng. Chem. Res., 48(2), 923 (2008)
Zhao JL, Guo L, Wang JY, J. Membr. Sci., 563, 957 (2018)
Das S, Kumar P, Dutta K, Kundu PP, Appl. Energy, 113, 169 (2014)
Ouadah A, Luo T, Gao S, Zhu C, Int. J. Hydrog. Energy, 43(32) (2018)
Yao H, Feng P, Liu P, Liu B, Zhang Y, Guan S, Jiang Z, Polym. Chem., 6(14), 2626 (2015)
Espiritu R, Mamlouk M, Scott K, Int. J. Hydrog. Energy, 41(2), 1120 (2016)
Sherazi TA, Sohn JY, Lee YM, Guiver MD, J. Membr. Sci., 441, 148 (2013)

[Referenced By]

[1] Warsinger DM, Prog. Polym. Sci., 81, 209 (2018)

[2] Goh PS, Matsuura T, Ismail AF, Hilal N, Desalination, 391, 43 (2016)

[3] Brant J, Kwan P, State-of-the-Science Review of Membrane Fouling: Organic, Inorganic, and Biological. Tech. Rep.06-10 (Phase A), California Department of water resources, 2013.

[4] Huang H, Schwab K, Jacangelo JG, Environ. Sci. Technol., 43(9), 3011 (2009)

[5] National Research Council, Water Reuse, National Academies Press, 2012.

[6] Cipollina A, Micale G, Rizzuti L(Eds.), Seawater Desalination: Conventional and Renewable Energy Processes, Springer Science & Business Media, 2009.

[7] Anderson MA, Cudero AL, Palma J, Electrochim. Acta, 55(12), 3845 (2010)

[8] Arnold BB, Murphy GW, J. Phys. Chem., 65(1), 135 (1961)

[9] Biesheuvel PM, Zhao R, Porada S, van der Wal A, J. Colloid Interface Sci., 360(1), 239 (2011)

[10] Luo T, Abdu S, Wessling M, J. Membr. Sci., 555, 429 (2018)

[11] Drent E, et al., Encyclopedia of Polymer Science and Technology, Polyketones, vol. 3, John Wiley, 2011.

[12] Jung YS, Canlier A, Hwang TS, Polymer, 141, 102 (2018)

[13] Hyosung Polyketone, http://www.poly-ketone.co.kr.

[14] Guo JT, Ye YQ, Gao S, Feng YK, J. Mol. Catal. A-Chem., 307(1-2), 121 (2009)

[15] Mul WP, Dirkzwager H, Broekhuis AA, Heeres HJ, van der Linden AJ, Orpen AG, Inorg. Chim. Acta., 327(1), 147 (2002)

[16] Bianchini C, Meli A, Coord. Chem. Rev., 225(1-2), 35 (2002)

[17] Rivas BL, Pereira ED, Moreno-Villoslada I, Prog. Polym. Sci., 28(2), 173 (2003)

[18] Zagorodni AA, Ion Exchange Materials: Properties and Applications, Elsevier, 2006.

[19] Ataollahi N, Vezzu K, Nawn G, Pace G, Cavinato G, Girardi F, Scardi P, Di Noto V, Di Maggio R, Electrochim. Acta, 226, 148 (2017)

[20] Ohsawa O, Lee KH, Kim BS, Lee S, Kim IS, Polymer, 51(9), 2007 (2010)

[21] Nam JU, Choi EY, Park HJ, Kim CK, Compos. Sci. Technol., 167, 199 (2018)

[22] Kim IS, Hwang CW, Kim YJ, Canlier A, Jeong KS, Hwang TS, Macromol. Res., 25(11), 1063 (2017)

[23] Banerjee S, Kar KK, Polymer, 109, 176 (2017)

[24] Mauritz KA, Moore RB, Chem. Rev., 104(10), 4535 (2004)

[25] Jin X, Bishop MT, Ellis TS, Karasz FE, Br. Polym. J., 17(1), 4 (1985)

[26] Wang F, Hickner M, Kim YS, Zawodzinski TA, McGrath JE, J. Membr. Sci., 197(1-2), 231 (2002)

[27] Knauth P, Hou H, Bloch E, Sgreccia E, Di Vona ML, J. Anal. Appl. Pyrolysis, 92(2), 361 (2011)

[28] Kumar M, Tripathi BP, Shahi VK, Ind. Eng. Chem. Res., 48(2), 923 (2008)

[29] Zhao JL, Guo L, Wang JY, J. Membr. Sci., 563, 957 (2018)

[30] Das S, Kumar P, Dutta K, Kundu PP, Appl. Energy, 113, 169 (2014)

[31] Ouadah A, Luo T, Gao S, Zhu C, Int. J. Hydrog. Energy, 43(32) (2018)

[32] Yao H, Feng P, Liu P, Liu B, Zhang Y, Guan S, Jiang Z, Polym. Chem., 6(14), 2626 (2015)

[33] Espiritu R, Mamlouk M, Scott K, Int. J. Hydrog. Energy, 41(2), 1120 (2016)

[34] Sherazi TA, Sohn JY, Lee YM, Guiver MD, J. Membr. Sci., 441, 148 (2013)