Ionic liquid (IL) aqueous solutions (aq) have emerged as promising candidates for SO, absorption. In this work, a new series of diamino polycarboxylate protic ionic liquids (DPPILs) aq with low viscosities and high stabilities were developed and used for SO2 capture. All of the prepared absorbents could efficiently absorb low-concentration SO2 in simulated flue gas. Among them, DPPILs aq based on citric acid (CA) presented the most excellent SO2 desorption performance; nearly all absorbed SO2 could be easily desorbed under mild conditions. Particularly, N,N-dimethylethylenediamine citrate [DMEDA] [CA] showed the highest available absorption capacity toward 0.2 vol % SO2 (up to 0.51 mol(SO2)/mol(ILS) and 0.058 g(SO2)/g(abs) in 50 wt % aq at 20 degrees C), which also presented satisfactory SO2/CO2 selectivity, reusability, and SO2 removal efficiency. Fourier transform infrared and nuclear magnetic resonance spectroscopic analyses revealed that the protonation of [DMEDA](+) and [CA](-) promoted SO2 absorption. Overall, the studied DPPILs aq with excellent physical properties, SO2 absorption-desorption performance, and stability may have a great perspective in industrial SO2 removal.