Journal of the American Chemical Society, Vol.119, No.16, 3732-3744, 1997
A Model for the Structure of the Large-Pore Zeolite Ssz-31
A model for the structure of the zeolite SSZ-31 is presented. The model is obtained by combining information from adsorption capacity measurements, transmission electron microscopy, and high-resolution X-ray diffraction. S52-31 is a one-dimensional large-pore zeolite with a framework density of 18.7 tetrahedral(T)-atoms per nm(-3) and a bulk density of 1.87 g cm(-3). The pore apertures are elliptical with major and minor axes of approximately 8.6 Angstrom x 5.7 Angstrom. SSZ-31 is an extreme example of a complex and highly faulted zeolite. The structure can be described as an intergrowth of four different but structurally related polymorphs.
Keywords:HIGH-SILICA ZEOLITE;FRAMEWORK TOPOLOGY;STRUCTURE-DIRECTION;POWDER DIFFRACTION;SHAPE SELECTIVITY;MOLECULAR-SIEVES;BETA;NCL-1