A series of novel sandwich-like GO@SiO2@C@Ni composites were developed. The morphologies and adsorption capacities of the materials sintered at different carbonization temperatures were investigated. The formed GO@SiO2@C@Ni-400 possessed of wonderful dispersion, large surface area (229.88 m(2)/g) and high saturation magnetization. Batch experimental results revealed that maximum adsorption capacities of these materials towards Cr(VI) were as follows: GO@SiO2@C@Ni-400 (299.20 mg/g) > GO@SiO2@C@ Ni-500 (244.05 mg/g) > GO (202.39 mg/g) > Graphene@C@Ni (188.80 mg/g) > GO@SiO2@C@Ni-600 (165.51 mg/g) > GO@SiO2@C@Ni-700 (93.36 mg/g). Moreover, the influence of hydrochemistry, such as contact time, pH, co-existing ions and solution temperature, on Cr(VI) adsorption was researched as well. It was demonstrated that GO@SiO2@C@Ni-400 had remarkable adsorption capacity for Cr(VI) removal under the acidic condition, hardly disturbed by other anions, and showed better adsorption performance at 328 K. Besides, On the base of X-ray photoelectron spectroscopy analysis, mechanisms of adsorption could be explained that Cr(VI) was reduced to Cr(III) by nitrogen dopant, and the complexation was existed between Cr(VI) and oxygen-containing functional groups. Additionally, GO@SiO2@C@Ni-400 could be easily separated under the external magnetic field and displayed outstanding reusability. Herein, GO@SiO2@C@Ni-400 opens up the possibility of future practical applications. (C) 2019 Elsevier Inc. All rights reserved.