Ternary metal sulfide based nanostructured materials are promising for commercialization of the electrochemical energy storage devices. Herein, three different NiCo2S4 nanostructures (nanoflakes, nanosheets, and nanoparticles) were fabricated by electrodeposition. Of these, nanosheets consisting of interconnected nanoparticles formed a highly porous network for supercapacitive energy storage. The electrochemical properties of each electrode were studied in detail and it was observed that the self-supported NiCo2S4 nanosheets possess a highest specific capacity of 590 mA h g(-1) (2655 F g(-1)) at 0.25 A g(-1) current density and cycling stability of 88.7% after 5000 charge-discharge cycles. This excellent behavior is attributed to several factors of the electrode such as high electrochemical active sites and ability of a nanostructure to withstand under high strain and accommodate large number of electrolyte ions during charge-discharge. The electrochemical storage properties of the NiCo2S4 nanosheets were further explored by fabricating battery-like solid-state asymmetric supercapacitor with activated carbon that delivered an ultra-high specific energy and power of 69.7 Wh kg(-1) and 8 kW kg(-1), respectively. These outcomes indicate that the novel nanostructured NiCo2S4 network has great potential for the development of energy storage devices. (C) 2019 Elsevier Inc. All rights reserved.