An Ag/AgCl/NH2-UiO-66 hybridized photocatalyst was successfully constructed via facile solvothermal with UV reduction method for efficient photocatalytic Cr (VI) reduction. The photoelectrochemical data indicate that compared with the UiO-66, the charge separation and transfer efficiency of Ag/AgCl/NH2-UiO-66 heterojunction is significantly enhanced due to the introduction of amine functionalization and formation of inorganic-organic hybrid. The surface plasmon resonance (SPR) effect deriving from Ag nanoparticles (NPs) largely extends photo-response range whilst the separation efficiency of photo generated electrons and holes is improved significantly. The synthesized Ag/AgCl/NH2-UiO-66 hybrid system shows ameliorated structural stability and superior photocatalytic activity for Cr (VI) reduction under visible light irradiation, which is 1.7 times higher than that of the bare UiO-66. Furthermore, the possible mechanism of Cr (VI) reduction is proposed by analyzing electron transfer path in the ternary Ag/AgCl/NH2-UiO-66 hybridized system. (C) 2019 Elsevier Inc. All rights reserved.