Spin coating technique is a simple and effective method to fabricate layered membranes and it has been widely used in the field of energy storage and transformation, biomaterials and electronics. The aim of this work is to develop anhydrous proton exchange membranes (PEMs) based on cheap polymers bearing the simple structure with spin coating technique. Successful fabrication of anhydrous PEMs based on polyvinylidene fluoride (PVDF) polymer, cadmium telluride (CdTe) nanocrystals and phosphoric acid (PA) molecules has been demonstrated by identification of high and stable proton conductivity. Specifically, (PVDF-CdTe-PA)(5)/85%PA membranes present the maximum proton conductivity of 7.70 x 10(-2) S/cm at 160 degrees C and 1.42 x 10(-2) S/cm at 140 degrees C lasting 620 h. The decreased proton conduction resistance is revealed from the drastic reduction of activation energy (Ea) owing to the layered structure and the adsorption of PA molecules. The introduction of CdTe nanocrystals to form the organic/inorganic composite membranes that is substantially more effective at improving proton conductivity and stiffness, showing great promise in solving the dilemma of proton conductivity and mechanical property. This study provides the support to exploit anhydrous PEMs with more cheap polymers using spin coating technique. (C) 2019 Elsevier Inc. All rights reserved.