The effective mass of the materials relies on exciton dynamics which is greatly dominated by energy gap of the materials. We examined the effective mass for the Al2O3/NiO nanoheterostructure material through polarization in the dielectric study. The mean optical effective mass was calculated to be m(opt)*, = 5.69645 X 10(-20) m(op)/m(0) in the UV-visible region (1 x 10(6) to 5.4 x 10(6) Hz). From the group and phase velocity values, we observed that Al2O3/NiO is an anisotropic material. The electron spin-orbit energy splitting associated to electron in the valence band was identified using the Gaussian-confining 3D potential under normalized angular momentum (n, 1 = 0, 1, 2, 3). The 1S (S-1(1/2)) and 2S (S-2(1/2)) orbital ionization energies were calculated to be -6.08 and -5.99 eV for AlO3/NiO. The orbital ionization energies were established from the Bohr radius a(B) = 5.29 X 10(-11) m and donor Rydberg constant R-y = 1.097 x 10(7) m(-1) of the identical hydrogen atom. Our study gives insights into the exciton dynamics and calculation of orbital energy for the nanoheterostructure materials.