Azobenzene switches its structure instantaneously by reversible trans-to-cis and cis-to-trans photoisomerization with light irradiations. Dynamic change in polymer structure is expected via introducing an azobenzene unit into the main chain. In this study, a set of methyl-substituted azobenzene-carbazole conjugated copolymers is synthesized by the Suzuki-Miyaura coupling method. Introduction of methyl substituents to the azobenzene unit of the monomer, and polymerization in a high-boiling solvent improve the molecular weight of the polymer. Decrease of effective conjugation length due to the twisted structure of the main chain allows progress of photoisomerization. The microstructure of the polymer was determined with grazing incidence X-ray diffraction (GIXD) measurements using synchrotron radiation. (c) 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019