Polymer-stabilized cholesteric liquid crystal (PSCLC) films with broadband reflection based on two-step photopolymerization are fabricated. Owing to the helical twisting power (HTP) value of the chiral dopant (CD) decreasing with increasing temperature, PSCLC films with broadband reflection are obtained by two-step polymerization anchoring helical pitch of different length at two different temperature points. The effect of monomer composition on the PSCLC reflection properties before and after polymerization was studied. The results show that the free-radical monomers with appropriate concentration and cationic monomers with sufficient concentration are vital for the formation of PSCLC films with broadband reflection. In addition, the experiments show that the increase in the functionality and rigidity of the cationic monomer has a positive effect on the broadening of the reflection band. This study can provide guidance and reference for the selection of monomer species and concentration in PSCLC preparation. (c) 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2019