화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.27, No.12, 1239-1247, December, 2019
DOI10.1007/s13233-019-7166-5  Export Citation
Sulfonated Cross-Linked Poly(ether ether ketone) Films with Wrinkled Structures: Preparation and Vanadium Ions Permeability
Abdul G. Al Lafi†, Reem Hasan, and Nedal Al-Kafri1
  • Department of Chemistry, Atomic Energy Commission, Damascus, P.O. Box 6091, Syrian Arab Republic
  • 1Department of Physics, Atomic Energy Commission, Damascus, P.O. Box 6091, Syrian Arab Republic
E-mail:
Wrinkling patterns were fabricated by sulfonation of ion irradiated poly(ether ether ketone) (PEEK). A variety of wrinkling patterns in the micrometer to sub-micrometer range were observed and were controlled by the adsorbed dose and dose rate of the irradiated ions as well as the sulfonation time. Because of the properties of these micro-textured membranes, they are promising for a broad range of applications. In particular, the cross-linked membranes had a very low permeability of vanadium ions, i.e. 1.5 × 10-7 cm2 min-1 due to their wrinkled structures in combination with the Donnan exclusive effect.
Keywords:ion irradiation;sulfonation;poly(ether ether ketone);wrinkled structure;permeability;vanadium ion
  1. Chapiro A, in High Polymers, John Wiley & Sons, Inc., New York, Vol. 15, pp 37-66 and 339-385, 1962.
  2. Charlesby A, Atomic Radiation and Polymers, Pergamon Press Ltd., London. 1960.
  3. Huntington MD, Engel CJ, Hryn AJ, Odom TW, ACS Appl. Mater. Interfaces, 5, 6438 (2013)
  4. Chen CM, Yang S, Polym. Int., 61, 1041 (2012)
  5. Ha JW, Park S, Macromol. Res., 25(1), 1 (2017)
  6. Najeeb S, Zafar MS, Khurshid Z, Siddiqui F, J. Prosth. Res., 60, 12 (2016)
  7. Sasuga T, Kudoh H, Polymer, 41(1), 185 (2000)
  8. EI-Sayed AH, Sasuga T, Seguchi T, Polymer, 33, 2911 (1992)
  9. Jung HY, Jeong S, Kwon Y, J. Electrochem. Soc., 163(1), A5090 (2016)
  10. Lee JW, Ahn YH, Kim DJ, Macromol. Res., 27(2), 175 (2019)
  11. Perry ML, Weber AZ, J. Electrochem. Soc., 163(1), A5064 (2016)
  12. Minke C, Turek T, J. Power Sources, 376, 66 (2018)
  13. Luo QT, Zhang HM, Chen J, You DJ, Sun CX, Zhang Y, J. Membr. Sci., 325(2), 553 (2008)
  14. Yan XM, Zhang CM, Dai Y, Zheng WJ, Ruan XH, He GH, J. Membr. Sci., 544, 98 (2017)
  15. Ji Y, Tay ZY, Li SFY, J. Membr. Sci., 539, 197 (2017)
  16. Al Lafi AG, Polym. Bull., 68(9), 2269 (2012)
  17. Al-Lafi AG, Hay JN, Parker DJ, J. Appl. Polym. Sci., 132, 4199 (2015)
  18. Al-Lafi AG, J. Appl. Polym. Sci., 131, 2593 (2014)
  19. Al Lafi AG, Hay JN, Thermochim. Acta, 612, 63 (2015)
  20. Kim JB, Kim P, Pegard NC, Oh SJ, Kagan CR, Fleischer JW, Stone HA, Loo YL, Nature Photonics, 6, 327 (2012)
  21. Lee JH, Ro HW, Huang R, Lemaillet P, Germer TA, Soles CL, Stafford CM, Nano Lett., 12, 5995 (2012)
  22. Bonaccurso E, Graf K, Langmuir, 20(25), 11183 (2004)
  23. Moon MW, Lee SH, Sun JY, Oh KH, Vaziri A, Hutchinson JW, PNAS, 104, 1130 (2007)
  24. Al Lafi AG, Hay JN, Parker DJ, J. Polym. Sci. B: Polym. Phys., 46(20), 2212 (2008)
  25. Shibuya N, Porter RS, Macromolecules, 25, 6495 (1992)
  26. Bishop MT, Karasz FE, Russet PS, Macromolecules, 18, 86 (1985)
  27. Al Lafi AG, Hay JN, J. Polym. Sci. B: Polym. Phys., 47(8), 775 (2009)
  28. Al Lafi AG, Hay JN, J. Appl. Polym. Sci., 128(5), 3000 (2013)
  29. Crank J, The Mathematics of Diffusion, Oxford University Press, New York, 1975.
  30. Di Vona ML, Marani D, D'Epifanio A, Licoccia S, Beurroies I, Denoyel R, Knauth P, J. Membr. Sci., 304(1-2), 76 (2007)
  31. Vona MLD, Sgreccia E, Licoccia S, Khadhraoui M, Denoyel R, Knauth P, Chem. Mater., 20, 4327 (2008)
  32. Qiu JY, Li MY, Ni JF, Zhai ML, Peng J, Xu L, Zhou HH, Li JQ, Wei GS, J. Membr. Sci., 297(1-2), 174 (2007)
  33. Luo QT, Zhang HM, Chen J, Qian P, Zhai YF, J. Membr. Sci., 311(1-2), 98 (2008)
  34. Al-Lafi AG, J. Appl. Polym. Sci., 132, Article No. 41242 (2015).
  35. Al-Lafi AG, J. Polym. Res., 25, 105 (2018)
  36. Staiti P, Lufrano F, Arico AS, Passalacqua E, Antonucci V, J. Membr. Sci., 188(1), 71 (2001)
  37. Poornesh KK, Cho C, Tak Y, Am. J. Mater. Sci., 5, 175 (2015)
  38. Yoo PJ, Electr. Mater. Lett., 7, 17 (2011)
  39. Kim J, Lee HH, J. Polym. Sci. B: Polym. Phys., 39(11), 1122 (2001)
  40. Yin J, Han X, Cao Y, Lu C, Sci. Rep., 4, 5710 (2014)
  41. Chung JY, Nolte AJ, Stafford CM, Adv. Mater., 21(13), 1358 (2009)
  42. Vandeparre H, Gabriele S, Brau F, Gay C, Parker KK, Damman P, Soft Matter, 6, 5751 (2010)
  43. Chandra D, Crosby AJ, Adv. Mater., 23(30), 3441 (2011)
  44. Uchida N, Ohzono T, Soft Matter, 6, 5729 (2010)
  45. Song JM, Shin J, Sohn JY, Nho YC, Macromol. Res., 19(10), 1082 (2011)
  46. Lee EB, Meng QB, Shin J, Lee YS, Macromol. Res., 22(10), 1090 (2014)
  47. Quan Y, Wang G, Li A, Wei X, Li F, Zhang J, Chen J, Wang R, RSC Adv., 9, 3838 (2019)
  48. Luo XL, Lu ZZ, Xi JY, Wu ZH, Zhu WT, Chen LQ, Qiu XP, J. Phys. Chem. B, 109(43), 20310 (2005)
  49. Jia CK, Liu JG, Yan CW, J. Power Sources, 195(13), 4380 (2010)
  50. Majsztrik PW, Satterfield MB, Bocarsly AB, Benziger JB, J. Membr. Sci., 301(1-2), 93 (2007)
  51. Kim S, Yan J, Schwenzer B, Zhang J, Li L, Liu J, Yang ZG, Hickner MA, Electrochem. Commun., 12, 1650 (2010)
  52. Zhang J, Wang G, Wang F, Zhang J, Chen J, Wang R, J. Electroanal. Chem., 783, 76 (2016)
  53. Ren J, Dong YC, Dai JC, Hu HL, Zhu YM, Teng XG, J. Membr. Sci., 544, 186 (2017)
  54. Sarkar S, SenGupta AK, Prakash P, Environ. Sci. Technol., 44, 1161 (2010)
  55. Chae IS, Luo T, Moon GH, Ogieglo W, Kang YS, Wessling M, Adv. Eng. Mater., 6, 160051 (2016)
  56. Xia ZJ, Ying LB, Fang JH, Du YY, Zhang WM, Guo XX, Yin J, J. Membr. Sci., 525, 229 (2017)