온도민감형 Poly(acrylamide-co-N-isopropyl acrylamide) 수화젤의 합성, 분석 그리고 흡습성

Seyda Tasar; Ramazan Orhan

Polymer(Korea), Vol.44, No.1, 49-60, January, 2020

DOI10.7317/pk.2020.44.1.49 Export Citation

온도민감형 Poly(acrylamide-co-N-isopropyl acrylamide) 수화젤의 합성, 분석 그리고 흡습성

Temperature-responsive Poly(acrylamide-co-N-isopropyl acrylamide) Hydrogel: Synthesis, Characterization, and Sorption Application

Seyda Tasar^†, and Ramazan Orhan

Department of Chemical Engineering, Firat University, 23279, Elazig, Turkey, Korea

E-mail:

Acrylamide-based hydrogels were used to remove cationic Basic Blue 3 (BB3) dye from aqueous solutions, in this study. First, acrylamide-based hydrogel was synthesized and characterized using SEM, FTIR and swelling analysis. The effects of various parameters were investigated to determine the removal of the BB3 dye from aqueous solutions. The sorption yield of BB3 dye of the hydrogel was determined to be 99%. The desorption efficiency was found to be above 90%. The sorption experimental data were evaluated using applying the Langmuir, Freundlich, Temkin, and Dubinin-Radushkevich (D-R) isotherm models. It was determined that the Langmuir was more suitable for isotherm the process. The maximum sorption capacity was calculated as 28.3 mg/g. Pseudo first order, pseudo second order, intraparticle diffusion, and Endovich kinetic models were used to calculate the kinetic parameters. It was concluded that the pseudo second-order kinetic model was described by the adsorption data very well.

Keywords:hydrogel;swelling ratios;sorption;kinetic and thermodynamic evaluation

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[Referenced By]

[1] Yangb MT, Sen TK, Afroze S, Ang HM, Colloid Polym. Sci., 209, 172 (2014)

[2] Bharathi KS, Ramesh ST, Appl. Water Sci., 3, 773 (2018)

[3] Dawood S, Sen TK, Water Res., 46, 1933 (2012)

[4] Vital RK, Saibaba KVN, Shaik KB, Gopinath R, J. Bioremediat. Biodegrad., 7, 1 (2016)

[5] Kaykhaii M, Sasani M, Marghzari S, Chem. Mater. Eng., 6, 31 (2018)

[6] Sivamani S, Grace BL, I.J.BST, 2, 47 (2009)

[7] Chincholi M, Sagwekar P, Nagaria C, Kulkarni S, Dhokpande S, IJSETR, 3, 835 (2014)

[8] Warade AR, Gaikwad RW, Sapkal RS, Sapkal VS, IJARIIE, 2, 3851 (2016)

[9] Mohammadi AS, Sardara M, Mohammadib A, Azimia F, Nurieh N, Archives of Hygiene Sciences, 2, 158 (2013).

[10] Sadeghi-Kiakhani M, Arami M, Gharanjig K, J. Environ. Chem. Eng., 1, 406 (2013)

[11] Jiang YH, Luo YY, Zhang FM, Guo LQ, Ni L, Appl. Surf. Sci., 273, 448 (2013)

[12] Attallah M, Ahmed I, Hamed MM, Environ. Sci. Pollut. Res., 20, 1106 (2013)

[13] Lin L, Zhai SR, Xiao ZY, Song Y, An QD, Song XW, Bioresour. Technol., 136, 437 (2013)

[14] Zhang Z, O'Hara IM, Kent GA, Doherty WOS, Ind. Crop. Prod., 42, 41 (2013)

[15] Li YH, Du QJ, Liu TH, Peng XJ, Wang JJ, Sun JK, Wang YH, Wu SL, Wang ZH, Xia YZ, Xia LH, Chem. Eng. Res. Des., 91(2), 361 (2013)

[16] Dotto GL, Moura JM, Cadaval TRS, Pinto LAA, Chem. Eng. J., 214, 8 (2013)

[17] Sadler BA, Metals L, Removal of Methylene Blue from Aqueous Solution Using a Novel Red Mud Mixed with Cement, John Wiley & Sons Inc., Hoboken, New Jersey, p 1-133 (2013).

[18] Roosta M, Ghaedi M, Shokri N, Daneshfar A, Sahraei R, Asghari A, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 118, 55 (2014)

[19] Zhou ZK, Lin SQ, Yue TL, Lee TC, J. Food Eng., 126, 133 (2014)

[20] Wang PF, Cao MH, Wang C, Ao YH, Hou J, Qian J, J. Appl. Surface Sci., 290, 116 (2014)

[21] Anirudhan TS, Ramachandran M, Process Saf. Environ. Protect., 95, 215 (2015)

[22] Ghaedi M, Shojaeipour E, Ghaedi AM, Sahraei R, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 142, 135 (2015)

[23] Premkumar Y, Vijayaraghavan K, Sep. Sci. Technol., 50(9), 1439 (2015)

[24] Kooli F, Yan L, Al-Faze R, Al-Sehimi A, Arab. J. Chem., 8, 33 (2015)

[25] Wawrzkiewicz M, Wigniewska M, Gun'ko VM, Zarko VI, Powder Technol., 278, 306 (2015)

[26] Chan SL, Tana YP, Abdullah AH, Ong ST, J. Taiwan Institute Chem. Eng., 61, 306 (2016)

[27] Banerjee S, Chattopadhyaya M, Arab. J. Chem., 10, 1629 (2017)

[28] Ibrahim AG, Hai FA, Abd El-Wahab H, Aboelanin H, Adv. Polym. Technol., 37, 3561 (2018)

[29] Kang SC, Zhao YL, Wang W, Zhang TT, Chen TX, Yi H, Rao F, Song SX, Appl. Surf. Sci., 448, 203 (2018)

[30] Sudarsan S, Franklin DS, Sakthivel M, Chitra G, Sridharan TB, Guhanathan S, J. Polym. Environ., 26, 3773 (2018)

[31] Saraydin D, Isikver Y, Karadag E, Polym. Eng. Sci., 58(3), 310 (2018)

[32] Dudu TE, Alpaslan D, Uzun Y, Int. J. Environ. Res., 11, 557 (2017)

[33] Bello K, Sarojini BK, Anjali BN, Byrappa RK, Carbohydr. Polym., 181, 605 (2018)

[34] Mohammed N, Grishkewich N, Berry RM, Tam KC, Cellulose, 22, 3725 (2015)

[35] Makhado E, Pandey S, Nomngongo PN, Ramontja J, J. Colloid Interface Sci., 513, 700 (2018)

[36] Wang W, Zhao Y, Bai H, Zhang T, Ibarra-Galvan V, Song S, Carbohydr. Polym., 198, 518 (2018)

[37] Ngwabebhoh FA, Gazi M, Oladipo AA, Chem. Eng. Res. Des., 112, 274 (2016)

[38] Panic VV, Velickovic SJ, Sep. Purif. Technol., 122, 384 (2014)

[39] Ghorai S, Sarkar A, Raoufi M, Panda AB, Schonherr H, Pal S, ACS Appl. Mater. Interfaces, 6, 4766 (2014)

[40] Akkaya R, Ulusoy U, Hacettepe J. Biol. Chem., 39, 359 (2011)

[41] Dumitrescu AM, Lisa G, Iordan AR, Tudorache F, Petrila I, Borhan AI, Palamaru MN, Mihailescu C, Leontie L, Munteanu C, Mater. Chem. Phys., 156, 170 (2015)

[42] Vijayaraghavan K, Yun YS, Biotechnol. Adv., 26, 266 (2008)