Preparation of pectin-based dual-crosslinked network as a binder for high performance Si/C anode for LIBs

Bolormaa Gendensuren; Chengxiang He; Eun-Suok Oh

Korean Journal of Chemical Engineering, Vol.37, No.2, 366-373, February, 2020

DOI10.1007/s11814-019-0438-0 Export Citation

Preparation of pectin-based dual-crosslinked network as a binder for high performance Si/C anode for LIBs

Bolormaa Gendensuren, Chengxiang He, and Eun-Suok Oh^†

School of Chemical Engineering, University of Ulsan, 93 Daehak-ro, Nam-gu, Ulsan 44610, Korea

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The modification of pectin polysaccharide through grafting with polyacrylamide and crosslinking is newly proposed as a powerful candidate for a water-soluble binder of high-capacity Si anodes in lithium ion batteries. The grafting of pectin with polyacrylamide enhances adhesion in the electrode and contributes to the good wettability of the carbonate electrolyte. Herein, dual-crosslinking of pectin-g-polyacrylamide was achieved by the ionic crosslinking of pectin with divalent calcium ions and the chemical crosslinking of polyacrylamide with a bisacrylamide. As a result, the dual-crosslinked binder improves further the cycling performance of the Si/C composite anode with a 1.2mg cm-2 loading, which retains a specific capacity of 729 mAh g-1 after 300 cycles. In contrast, the Si/C electrode containing dual-crosslinked alginate with polyacrylamide shows a specific capacity of 515mAh g-1 after 300 cycles.

Keywords:Polyacrylamide;Binder;Dual-crosslinked Polymer;Lithium-ion Battery;Silicon/Graphite High Capacity Electrode

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[3] Li B, Wang Y, Yang S, Adv. Eng. Mater., 8, 170229 (2018)

[4] Buqa H, Holzapfel M, Krumeich F, Veit C, Novak P, J. Power Sources, 161(1), 617 (2006)

[5] Liu WR, Yang MH, Wu HC, Chiao SM, Wu NL, Electrochem. Solid-State Lett., 8, A100 (2005)

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[8] Li J, Lewis RB, Dahn JR, Electrochem. Solid-State Lett., 10, A17 (2007)

[9] Kovalenko I, Zdyrko B, Magasinski A, Hertzberg B, Milicev Z, Burtovyy R, Luzinov I, Yushin G, Science, 334, 75 (2011)

[10] Lin N, Han Y, Wang L, Zhou J, Zhou J, Zhu Y, Qian Y, Angew. Chem.-Int. Edit., 54, 3822 (2015)

[11] Yi Z, Wang W, Qian Y, Liu X, Lin N, Qian Y, ACS Sustainable Chem. Eng., 6, 14230 (2018)

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[13] Zhang L, Zhang L, Chai L, Xue P, Hao W, Zheng H, J. Mater. Chem. A, 2, 19036 (2014)

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[18] Yoon DE, Hwang C, Kang NR, Lee U, Ahn D, Kim JY, Song HK, ACS Appl. Mater. Interfaces, 8, 4042 (2016)

[19] Chauhan GS, Kumari A, Sharma R, J. Appl. Polym. Sci., 106(4), 2158 (2007)

[20] da Silva MA, Bierhalz ACK, Kieckbusch TG, Carbohydr. Polym., 77, 736 (2009)

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[22] Zhu X, Zhang F, Zhang L, Zhang L, Song Y, Jiang T, Sayed S, Lu C, Wang X, Sun J, Liu Z, Adv. Funct. Mater., 28, 170501 (2018)

[23] Gendensuren B, Oh ES, J. Power Sources, 384, 379 (2018)

[24] Sun JY, Zhao X, Illeperuma WRK, Chaudhuri O, Oh KH, Mooney DJ, Vlassak JJ, Suo Z, Nature, 489, 133 (2012)

[25] Luo L, Xu Y, Zhang H, Han X, Dong H, Xu X, Chen C, Zhang Y, Lin J, ACS Appl. Mater. Interfaces, 8, 8154 (2016)

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[28] Biswal DR, Singh RP, Carbohydr. Polym., 57, 379 (2004)

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[30] Nguyen MHT, Oh ES, Electrochem. Commun., 35, 45 (2013)

[31] Lee BR, Kim SJ, Oh ES, J. Electrochem. Soc., 161(14), A2128 (2014)

[32] Takami N, Satoh A, Hara M, Ohsaki I, J. Electrochem. Soc., 142(2), 371 (1995)

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