Mesoporous Hierarchically Hollow Flower-Like CoAl-LDH@N,S-doped Graphene@Pd Nanoarchitectures for Heck Couplings

Rohani S; Ziarani GM; Badiei A; Ziarati A; Luque R

Catalysis Letters, Vol.149, No.11, 2984-2993, 2019

DOI10.1007/s10562-019-02880-x Export Citation

Mesoporous Hierarchically Hollow Flower-Like CoAl-LDH@N,S-doped Graphene@Pd Nanoarchitectures for Heck Couplings

Rohani S, Ziarani GM, Badiei A, Ziarati A, Luque R

A smart strategy for the synthesis of hierarchical CoAl-LDH hollow spheres assembled with nitrogen and sulfur co-doped graphene for high holding of palladium nanoparticles (CoAl-LDH@N,S-G@Pd) is reported. This architecture exhibited excellent activity in Heck reactions with TOF as high as 1633 h(-1) due to a strong metal-support interaction, good electron transfers and high surface area.

Keywords:Heterogeneous catalysis;Heck coupling;Nanostructure;Layered double hydroxide;N, S doped graphene