화학공학소재연구정보센터
Journal of Colloid and Interface Science, Vol.562, 567-577, 2020
Facile fabrication of thin metal oxide films on porous carbon for high density charge storage
In an effort to minimize the usage of non-renewable materials and to enhance the functionality of the renewable materials, we have developed thin metal oxide coated porous carbon derived from a highly abundant non-edible bio resource, i.e., palm kernel shell, using a one-step activation-coating procedure and demonstrated their superiority as a supercapacitive energy storage electrode. In a typical experiment, Oan optimized composition contained similar to 10 wt% of Mn2O3 on activated carbon (AC); a supercapacitor electrode fabricated using this electrode showed higher rate capability and more than twice specific capacitance than pure carbon electrode and could be cycled over 5000 cycles without any appreciable capacity loss in 1 M Na2SO4 electrolyte. A symmetric supercapacitor prototype developed using the optimum electrode showed nearly four times higher energy density than the pure carbon owing to the enhancements in voltage window and capacitance. A lithium ion capacitor fabricated in half-cell configuration using 1 M LiPF6 electrolyte showed larger voltage window, superior capacitance and rate capability in the similar to 10 wt% Mn2O3 @AC than the pure analogue. These results demonstrate that the current protocol allows fabrication of superior charge storing electrodes using renewable materials functionalized by minimum quantity of earthborn materials. (C) 2019 Elsevier Inc. All rights reserved.