Powder Technology, Vol.356, 1059-1076, 2019
Comparing the strengthening efficiency of multiwalled carbon nanotubes and graphene nanoplatelets in aluminum matrix
The research work comprehensively evaluates and compares the strengthening efficiency of multiwalled carbon nanotubes (MWCNTs) and graphene nanoplatelets (GNPs), two of the most promising nano-size reinforcements, which could be employed for fabricating high strength-low weight nanocomposites. High energy ball milled Al powder and different loadings of CNT and GNP (0.5 and 1.0 wt%) were mixed and subsequently consolidated via spark plasma sintering to synthesize Al-CNT and Al-GNP nanocomposites. A clean Al-CNT/GNP interface devoid of traces of any micro-pores and reaction products was achieved. Al-1.0 wt% CNT/GNP showed lower crystallite size and relative density as compared to Al-0.5 wt% CNT/GNP counterpart. Al-1.0 wt% GNP exhibited the lowest relative density (96%) owing to very high volume and surface area of GNP which resulted in rapid agglomeration. Al-CNT nanocomposites exhibited better compression properties as compared to Al-GNP nanocomposites. During compression, for 0.5 wt% reinforcement, the reinforcing efficiency of CNT was 12.4, whereas, that of GNP was 53. Tensile test revealed that as compared to milled Al powder compact, Al-0.5 wt% CNT and Al-0.5 wt% GNP exhibited 70% and 85% higher yield strength, respectively. The contributions from different strengthening mechanisms were calculated to predict the yield strength of the sintered nanocomposites. It was found that, for 0.5 wt% reinforced CNT and GNP, the experimentally obtained yield strength of respective nanocomposites were about 91% and 97% closer to the predicted values confirming the effective translation of different strengthening mechanisms towards the strength of the nanocomposites. Further increase in the CNT/GNP content to 1.0 wt% led to deterioration in the compression and tensile properties due to extensive aggregation of respective reinforcements in the Al matrix and the extent of deterioration was substantial for Al-1.0GNP. (C) 2019 Elsevier B.V. All rights reserved.
Keywords:Metal matrix nanocomposite;Multiwalled carbon nanotube;Graphene nanoplatelet;Reinforcing efficiency;Compression properties;Tensile properties