Integrating photovoltaics into windows provides the possibility of including an additional function of energy production to a conventional building fenestration component. There is no doubt that electrical power can be generated on-site. However, the effect of PV windows on the indoor luminous environment of the space served by them has not been comprehensively researched. This paper investigated the daylight performance of integrating four types of photovoltaics (semi-transparent thin film Cadmium telluride (CdTe) solar cells with 10% and 50% transparency, crystalline silicon solar cells with and without crossed compound parabolic concentrators (CCPC)) to a window of a typical south-facing office under different Window-to-Wall Ratios (WWRs). Annual useful daylight illuminance (UDI), daylight uniformity ratio (UR) and daylight glare probability (DGP) have been analysed based on dynamic simulation using RADIANCE. The simulation results show that windows integrated with crystalline silicon cells and CCPC optics have the potential to provide best daylight availability when compared with standard double glazed windows and other tested PV window prototypes, if it is applied to rooms with large WWRs (e.g. 60% or 75% WWR) at high latitudes (e.g. city of Harbin). Its application also improves the uniformity of daylight spatial distribution and eliminates the risk of glare. Semi-transparent CdTe PV window with 10% transparency can also improve the percentage of working hours that fall into UDI (500-2000lux) range, however, it will result in the most sharp illuminance contrasts within the room. Applying all of these tested PV windows can effectively reduce the possibility of glare. (C) 2019 Elsevier Ltd. All rights reserved.